Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide
文献类型：期刊论文
| 作者 | Li,Zong-Jun ; Li,Shu-Hui ; Sun,Tao ; Gao,Xiang |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 79期号:1页码:197-203 |
| 关键词 | FULLERENE DIMER 2+2 CYCLOADDITION DERIVATIVES C-120 FULLEROOXAZOLES ADDUCT R3C60 NMR |
| 通讯作者 | gao,x |
| 英文摘要 | oxazoline and imidazoline functionalization of a singly bonded c-60 dimer is achieved via a one-pot reaction of c60hbn with oh- and aromatic nitriles, where the oh- not only functions as a bronsted base that deprotonates c60hbn but also as a nucleophile that initiates the nucleophilic addition to the fullerene cage. the structures of the obtained oxazolinated and imidazolinated c-60 dimeric compounds have been established by hrms, uv-vis, and h-1, c-13, and hmbc nmr characterizations and computational calculations. the reaction mechanism is studied with the in situ vis-near-ir spectra, which shows that the use of i-2 is crucial for the functionalization of the c-60 dimer, indicating that it is likely the dimeric molecule rather than the fragment of the dimer that is involved in the reaction. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/56222]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,et al. Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide[J]. journal of organic chemistry,2014,79(1):197-203. |
| APA | Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,&Gao,Xiang.(2014).Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide.journal of organic chemistry,79(1),197-203. |
| MLA | Li,Zong-Jun,et al."Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide".journal of organic chemistry 79.1(2014):197-203. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。