Reductive Benzylation of C-70 Imidazoline with a Bulky Addend
文献类型：期刊论文
| 作者 | Hou,Hui-Lei ; Li,Zong-Jun ; Wang,Ying ; Gao,Xiang |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 79期号:18页码:8865-8870 |
| 关键词 | SOLAR-CELLS FULLERENES DERIVATIVES EQUATORIAL CHEMISTRY C-60 ACCEPTORS ADDUCT |
| 通讯作者 | gao,x |
| 英文摘要 | reductive benzylation of c-70 imidazolines bearing a bulky addend has been carried out under conditions similar to that reported for c-60 analogues. however, different from the reaction of c-60 analogues, the reaction of c-70 imidazolines not only results in adducts with 1,2,3,16-configuration due to the steric effect, but also a considerable amount of dibenzylated and monobenzylated products with 1,2,3,4-configuration, demonstrating a reactivity difference between c-60 and c-70. interestingly, the anions of the 1,2,3,16-c-70 adduct are rather stable as shown by the electrochemical study, which is in contrast to the anions of 1,2,3,16-c-60 counterparts, and can be rationalized by the electronic structure difference between c-70 and c-60 derivatives. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/56223]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hou,Hui-Lei,Li,Zong-Jun,Wang,Ying,et al. Reductive Benzylation of C-70 Imidazoline with a Bulky Addend[J]. journal of organic chemistry,2014,79(18):8865-8870. |
| APA | Hou,Hui-Lei,Li,Zong-Jun,Wang,Ying,&Gao,Xiang.(2014).Reductive Benzylation of C-70 Imidazoline with a Bulky Addend.journal of organic chemistry,79(18),8865-8870. |
| MLA | Hou,Hui-Lei,et al."Reductive Benzylation of C-70 Imidazoline with a Bulky Addend".journal of organic chemistry 79.18(2014):8865-8870. |
入库方式： OAI收割
来源：长春应用化学研究所
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