Cu-Mediated Direct Aryl C-H Halogenation: a Strategy to Control Mono- and Di-Selectivity
文献类型：期刊论文
| 作者 | Du, Zhi-Jun ; Gao, Lian-Xun ; Lin, Ying-Jie ; han,Fu-She |
| 刊名 | chemcatchem
 |
| 出版日期 | 2014 |
| 卷号 | 6期号:1页码:123-126 |
| 关键词 | COUPLING REACTIONS CATALYTIC METHOD BOND PALLADIUM HALIDES COPPER BROMINATION ARYLATION ARENES FUNCTIONALIZATIONS |
| 通讯作者 | han,fs |
| 英文摘要 | a protocol for the copper-mediated direct aryl ch halogenation is presented. highly selective mono- and di-halogenations are achieved by using acyl hypohalites, generated insitu from the readily available carboxylic acid and n-halosuccinimides (nxs; x=br and cl) as powerful halogenating reagents. the correct choice of carboxylic acid additives and solvents is essential for both high yield and selectivity. consequently, the use of inexpensive cu catalyst and the new strategy for the insitu generation of acyl hypohalite halogenating reagents from the readily affordable and easily-to-handle carboxylic acid and nxs (x=br and cl) offers advantages for practical application. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/56242]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Du, Zhi-Jun,Gao, Lian-Xun,Lin, Ying-Jie,et al. Cu-Mediated Direct Aryl C-H Halogenation: a Strategy to Control Mono- and Di-Selectivity[J]. chemcatchem,2014,6(1):123-126. |
| APA | Du, Zhi-Jun,Gao, Lian-Xun,Lin, Ying-Jie,&han,Fu-She.(2014).Cu-Mediated Direct Aryl C-H Halogenation: a Strategy to Control Mono- and Di-Selectivity.chemcatchem,6(1),123-126. |
| MLA | Du, Zhi-Jun,et al."Cu-Mediated Direct Aryl C-H Halogenation: a Strategy to Control Mono- and Di-Selectivity".chemcatchem 6.1(2014):123-126. |
入库方式： OAI收割
来源：长春应用化学研究所
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