Solvent micro-evaporation and concentration gradient synergistically induced crystallization of poly(L-lactide) and ring banded supra-structures with radial periodic variation of thickness
文献类型：期刊论文
| 作者 | Huang, Shaoyong ; Li, Hongfei ; Wen, Huiying ; Yu,Donghong ; Jiang,Shichun ; Li,Gao ; Chen,Xuesi ; An,Lijia |
| 刊名 | crystengcomm
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:1页码:94-101 |
| 关键词 | SPHERULITIC GROWTH-RATES THIN-FILMS DIBLOCK COPOLYMERS RHYTHMIC GROWTH POLY(EPSILON-CAPROLACTONE) SOLUTION SEMICRYSTALLINE POLYMER ISOTACTIC POLYSTYRENE MISCIBLE MIXTURES CRYSTAL-STRUCTURE MELTING BEHAVIOR |
| 通讯作者 | huang,sy |
| 英文摘要 | the crystalline morphology and structure of poly(l-lactide) (plla) in a plla film-chloroform system were investigated by means of wide angle x-ray diffraction (waxd), polarized optical microscopy (pom) and atomic force microscopy (afm). birefringent and nonbirefringent ring banded supra-structures with radial periodic variation of thickness were obtained, which were induced by micro-evaporation of solvents and concentration gradient of plla. the ring banded morphologies consisted of multilayer lamellar crystals, which is a manifestation of alternating ridge and valley bands of periodic variation of thicknesses along the radial direction. the formation of the ring banded supra-structures is associated with diffusion and crystal growth induced periodic variation of concentration gradient, which is attributed to diffusion-related rhythmic growth and the competition between diffusion of polymer segments and growth of crystal lamellae. the mechanism of such banded-ring formation was explored on the basis of rhythmic growth resulting from non-linear diffusion. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57220]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Huang, Shaoyong,Li, Hongfei,Wen, Huiying,et al. Solvent micro-evaporation and concentration gradient synergistically induced crystallization of poly(L-lactide) and ring banded supra-structures with radial periodic variation of thickness[J]. crystengcomm,2014,16(1):94-101. |
| APA | Huang, Shaoyong.,Li, Hongfei.,Wen, Huiying.,Yu,Donghong.,Jiang,Shichun.,...&An,Lijia.(2014).Solvent micro-evaporation and concentration gradient synergistically induced crystallization of poly(L-lactide) and ring banded supra-structures with radial periodic variation of thickness.crystengcomm,16(1),94-101. |
| MLA | Huang, Shaoyong,et al."Solvent micro-evaporation and concentration gradient synergistically induced crystallization of poly(L-lactide) and ring banded supra-structures with radial periodic variation of thickness".crystengcomm 16.1(2014):94-101. |
入库方式： OAI收割
来源：长春应用化学研究所
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