Water crystallization to create ice spacers between graphene oxide sheets for highly electroactive graphene paper
文献类型:期刊论文
作者 | Chen, Kunfeng ; Liu, Fei ; Song, Shuyan ; Xue,Dongfeng |
刊名 | crystengcomm
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出版日期 | 2014 |
卷号 | 16期号:33页码:7771-7776 |
关键词 | EXCELLENT PSEUDOCAPACITOR ELECTRODE AQUEOUS-SOLUTIONS NANOPARTICLES PERFORMANCE SYSTEM SALT |
通讯作者 | chen,kf |
英文摘要 | we proved that ice crystallized from water molecules within as-synthesized graphene oxide (go) can be used as a spacer among individual go sheets to form an expanded go aerogel with a three-dimensional porous network structure. this designed specific structure can be retained during further processes to form graphene paper. due to the fact that the as-fabricated graphene paper contains carbon defects and space in its infrastructure, this creates more electroactive surfaces and interfaces to significantly increase the faradaic reaction efficiency. with the introduction of redox-electrolyte k3fe(cn)(6) into a koh electrolyte, we can obtain a 95-fold increase in the specific capacitance compared with the value obtained in the traditional koh electrolyte. the ice-crystallization formed graphene paper electrode showed high electro-activity because the specific porous structure can favor the fast transfer of electrolyte ions, such as fe(cn)(6)(3-) ions. the presented results prove that ice-crystallization formed go can serve as a chemically tunable platform for electrochemical energy storage applications. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-10-27 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57232] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Chen, Kunfeng,Liu, Fei,Song, Shuyan,et al. Water crystallization to create ice spacers between graphene oxide sheets for highly electroactive graphene paper[J]. crystengcomm,2014,16(33):7771-7776. |
APA | Chen, Kunfeng,Liu, Fei,Song, Shuyan,&Xue,Dongfeng.(2014).Water crystallization to create ice spacers between graphene oxide sheets for highly electroactive graphene paper.crystengcomm,16(33),7771-7776. |
MLA | Chen, Kunfeng,et al."Water crystallization to create ice spacers between graphene oxide sheets for highly electroactive graphene paper".crystengcomm 16.33(2014):7771-7776. |
入库方式: OAI收割
来源:长春应用化学研究所
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