Synergistic effects of ion pairs on the dielectric properties of diblock copolymer melts
文献类型:期刊论文
作者 | Nakamura, Issei |
刊名 | soft matter
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出版日期 | 2014 |
卷号 | 10期号:48页码:9596-9600 |
关键词 | RECHARGEABLE LITHIUM BATTERIES BLOCK-COPOLYMERS POLYMER BLENDS SOLVATION LIQUIDS POLAR SALT THERMODYNAMICS IONOMERS |
通讯作者 | nakamura,i |
英文摘要 | we study the solvation of ion pairs in diblock copolymer melts. our theory accounts for the size of the ions, the permanent dipole moment and the molecular polarizability of the monomers, the kuhn length, the compressibility of the liquid mixtures, and the degrees of polymerization. we demonstrate that the electrostatic field near an ion pair causes marked, synergistic effects on the volume fractions of the two blocks and hence the dielectric function. in particular, we illustrate the oscillatory behavior of the dielectric function near an ion pair and the disparity of the dielectric functions between like and unlike charges. these results depend significantly on the chain length and kuhn length of the diblock copolymers on the nanometer scale. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000345530400001 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57238] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Nakamura, Issei. Synergistic effects of ion pairs on the dielectric properties of diblock copolymer melts[J]. soft matter,2014,10(48):9596-9600. |
APA | Nakamura, Issei.(2014).Synergistic effects of ion pairs on the dielectric properties of diblock copolymer melts.soft matter,10(48),9596-9600. |
MLA | Nakamura, Issei."Synergistic effects of ion pairs on the dielectric properties of diblock copolymer melts".soft matter 10.48(2014):9596-9600. |
入库方式: OAI收割
来源:长春应用化学研究所
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