The solvent-dependent binding modes of a rhodamine-azacrown based fluorescent probe for Al3+ and Fe3+
文献类型：期刊论文
| 作者 | Fang,Xinxiu ; Zhang,Shoufeng ; Zhao,Guiyan ; Zhang,Wenwen ; Xu,Jingwei ; Ren,Aimin ; Wu,Cunqi ; Yang,Wei |
| 刊名 | dyes and pigments
 |
| 出版日期 | 2014 |
| 卷号 | 101期号:2页码:58-66 |
| 关键词 | PHOTOINDUCED ELECTRON-TRANSFER DUAL-CHANNEL FLUORESCENCE AQUEOUS-MEDIA ALUMINUM IONS LIVING CELLS LOGIC GATE CHEMOSENSOR CONJUGATE SENSOR IRON |
| 通讯作者 | ren,am |
| 英文摘要 | a rhodamine-azacrown derivative (2-(2-(1,4-dioxa-7,13-dithia-10-azacyclo- pentadecan-10-yl)ethyl)-3',6'-bis(diethyl amino)spiro[isoindoline-1,9'-xanthen]-3-one) responded to al3+ and fe3+ in ethanol-water solutions (20/80, v/v, ph = 7.0) and selectively responded to al3+ in acetonitrile. in addition, it bound to the cation with a simple 1:1 mode in aqueous solutions and 2:1 mode in acetonitrile. the association constants (logka) of the sensor for fe3+ and al3+ were obtained to be 6.5 and 3.6 in ethanol water, and the corresponding detection limits were calculated to be 1.2 and 8.6 x 10(-8) m, respectively, while the association constant (logka) for al3+ was 3.9 with a detection limit of 5.9 x 10(-7) m in acetonitrile under our experimental conditions. nuclear magnetic resonance and other investigations indicated that in acetonitrile the existence of the second al3+ shifted the binding location of the first al3+, which led to the spirolactam ring-open and fluorescence formation. the mechanisms for the sensor to al3+ and fe3+ in different solvents are discussed in detail. (c) 2013 elsevier ltd. all rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57239]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Fang,Xinxiu,Zhang,Shoufeng,Zhao,Guiyan,et al. The solvent-dependent binding modes of a rhodamine-azacrown based fluorescent probe for Al3+ and Fe3+[J]. dyes and pigments,2014,101(2):58-66. |
| APA | Fang,Xinxiu.,Zhang,Shoufeng.,Zhao,Guiyan.,Zhang,Wenwen.,Xu,Jingwei.,...&Yang,Wei.(2014).The solvent-dependent binding modes of a rhodamine-azacrown based fluorescent probe for Al3+ and Fe3+.dyes and pigments,101(2),58-66. |
| MLA | Fang,Xinxiu,et al."The solvent-dependent binding modes of a rhodamine-azacrown based fluorescent probe for Al3+ and Fe3+".dyes and pigments 101.2(2014):58-66. |
入库方式： OAI收割
来源：长春应用化学研究所
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