Synthesis and characterization of a novel organophosphorus oligomer and its application in improving flame retardancy of epoxy resin
文献类型：期刊论文
| 作者 | Tian, Nana ; Gong, Jiang ; Wen, Xin ; Yao,Kun ; Tang,Tao |
| 刊名 | rsc advances
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:34页码:17607-17614 |
| 关键词 | CAGED BICYCLIC PHOSPHATE THERMAL-DEGRADATION AMMONIUM POLYPHOSPHATE CHARRING AGENT POLYPROPYLENE COMPOSITES SILICON PHOSPHORUS INTUMESCENCE COMBUSTION |
| 通讯作者 | tang,t |
| 英文摘要 | a novel organophosphorus, poly(4,4-dihydroxy-1-methyl-ethyl diphenol-o-bicyclic pentaerythritol phosphatephosphate) (pcpbo), was synthesized and characterized by ftir, h-1 nmr and p-31 nmr. the flame retardancy and thermal stability of epoxy resin with different pcpbo loadings were investigated using the limited oxygen index (loi), vertical burning test, cone calorimeter test and thermogravimetric analysis. the results showed that the incorporation of pcpbo into epoxy resin (ep) significantly improved its flame retardancy and thermal stability. the reduction of the peak heat release rate, total heat release and the increased char yield at high temperature further confirmed the improvement of the flame retardancy. ft-ir at different temperatures and the scanning electron microscopy of residual char revealed that the addition of pcpbo could induce the formation of an intumescent char layer, which retarded the degradation and combustion process of ep. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000335227700026 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57260]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tian, Nana,Gong, Jiang,Wen, Xin,et al. Synthesis and characterization of a novel organophosphorus oligomer and its application in improving flame retardancy of epoxy resin[J]. rsc advances,2014,4(34):17607-17614. |
| APA | Tian, Nana,Gong, Jiang,Wen, Xin,Yao,Kun,&Tang,Tao.(2014).Synthesis and characterization of a novel organophosphorus oligomer and its application in improving flame retardancy of epoxy resin.rsc advances,4(34),17607-17614. |
| MLA | Tian, Nana,et al."Synthesis and characterization of a novel organophosphorus oligomer and its application in improving flame retardancy of epoxy resin".rsc advances 4.34(2014):17607-17614. |
入库方式： OAI收割
来源：长春应用化学研究所
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