Divergent synthesis of 2,3-dihydro-1H-pyrroles, 3-alkyl-1H-pyrroles and 3-alkenyl-1H-pyrroles from 2,4-pentadienenitriles and isocyanides
文献类型：期刊论文
| 作者 | Xin, Xiaoqing ; Liu, Xu ; Zhang, Dingyuan ; Zhang,Rui ; Liang,Yongjiu ; Hana,Fushe ; Dong,Dewen |
| 刊名 | organic & biomolecular chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 12期号:29页码:5477-5483 |
| 关键词 | HIGHLY REGIOSELECTIVE SYNTHESIS SUBSTITUTED PYRROLES NITROGEN-HETEROCYCLES EXOCYCLIC RINGS DERIVATIVES ALKALOIDS MULTICOMPONENT CYCLOADDITION INDOLIZINES REARRANGEMENT |
| 通讯作者 | liang,yj |
| 英文摘要 | an efficient and divergent one-pot synthesis of 2,3-dihydro-1h-pyrroles, 3-alkyl-1h-pyrroles and 3-alkenyl-1h-pyrroles from readily accessible 2,4-pentadienenitriles with isocyanide based on reaction condition selection has been described. the reaction of 2,4-pentadienenitriles with ethyl isocyanoacetate undergoes a formal [2 + 3] annulation either to generate 2,3-dihydro-1h-pyrroles in the presence of dbu (0.3 equiv.) in etoh at room temperature or to give 3-alkyl-1h-pyrroles in the presence of dbu (2.0 equiv.) in etoh under reflux. moreover, the 2,3-dihydro-1h-pyrroles could be converted to 3-alkenyl-1h-pyrroles with ddq as an oxidant. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57320]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xin, Xiaoqing,Liu, Xu,Zhang, Dingyuan,et al. Divergent synthesis of 2,3-dihydro-1H-pyrroles, 3-alkyl-1H-pyrroles and 3-alkenyl-1H-pyrroles from 2,4-pentadienenitriles and isocyanides[J]. organic & biomolecular chemistry,2014,12(29):5477-5483. |
| APA | Xin, Xiaoqing.,Liu, Xu.,Zhang, Dingyuan.,Zhang,Rui.,Liang,Yongjiu.,...&Dong,Dewen.(2014).Divergent synthesis of 2,3-dihydro-1H-pyrroles, 3-alkyl-1H-pyrroles and 3-alkenyl-1H-pyrroles from 2,4-pentadienenitriles and isocyanides.organic & biomolecular chemistry,12(29),5477-5483. |
| MLA | Xin, Xiaoqing,et al."Divergent synthesis of 2,3-dihydro-1H-pyrroles, 3-alkyl-1H-pyrroles and 3-alkenyl-1H-pyrroles from 2,4-pentadienenitriles and isocyanides".organic & biomolecular chemistry 12.29(2014):5477-5483. |
入库方式： OAI收割
来源：长春应用化学研究所
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