Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator
文献类型:期刊论文
作者 | Ding, Zicheng ; Chen, Bo ; Ding, Junqiao ; Wang,Lixiang ; Han,Yanchun |
刊名 | journal of colloid and interface science
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出版日期 | 2014 |
卷号 | 425期号:1页码:102-109 |
关键词 | ORGANOPHOSPHORUS HYBRID NANORODS PHOSPHATE GELS ORGANOGELS METAL ALUMINOPHOSPHATES DENDRIMERS COORDINATION SPECTROSCOPY SURFACTANT |
通讯作者 | han,yc |
英文摘要 | supramolecular metallogels can be gained from the phosphonate substituted 4,4'-bis(n-carbazolyl)biphenyl (pcbp) in the presence of aluminum chloride in alcohols, which can donate oxygen to aid proton transfer in the aluminum organophosphorus complexes. inside the metallogels, three-dimensional fiber networks with nanofibers entangling and intersecting with each other inside are formed. the nanofibers show layered structures with a period thickness of 0.82 nm. as the content of aluminum(iii) increases, the size of the fibers becomes smaller and the fibers pack more densely. it makes the transparent gel become turbid but nevertheless improves the stability of the metallogels. nmr, ft-ir and fluorescence spectroscopy show that the coordination interactions between the phosphonate groups of pcbp molecules and aluminum(iii) ions as well as the pi-pi interactions among pcbp molecules are involved during the gel formation process. (c) 2014 elsevier inc. all rights reserved. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000335620500015 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57336] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Ding, Zicheng,Chen, Bo,Ding, Junqiao,et al. Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator[J]. journal of colloid and interface science,2014,425(1):102-109. |
APA | Ding, Zicheng,Chen, Bo,Ding, Junqiao,Wang,Lixiang,&Han,Yanchun.(2014).Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator.journal of colloid and interface science,425(1),102-109. |
MLA | Ding, Zicheng,et al."Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator".journal of colloid and interface science 425.1(2014):102-109. |
入库方式: OAI收割
来源:长春应用化学研究所
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