中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator

文献类型:期刊论文

作者Ding, Zicheng ; Chen, Bo ; Ding, Junqiao ; Wang,Lixiang ; Han,Yanchun
刊名journal of colloid and interface science
出版日期2014
卷号425期号:1页码:102-109
关键词ORGANOPHOSPHORUS HYBRID NANORODS PHOSPHATE GELS ORGANOGELS METAL ALUMINOPHOSPHATES DENDRIMERS COORDINATION SPECTROSCOPY SURFACTANT
通讯作者han,yc
英文摘要supramolecular metallogels can be gained from the phosphonate substituted 4,4'-bis(n-carbazolyl)biphenyl (pcbp) in the presence of aluminum chloride in alcohols, which can donate oxygen to aid proton transfer in the aluminum organophosphorus complexes. inside the metallogels, three-dimensional fiber networks with nanofibers entangling and intersecting with each other inside are formed. the nanofibers show layered structures with a period thickness of 0.82 nm. as the content of aluminum(iii) increases, the size of the fibers becomes smaller and the fibers pack more densely. it makes the transparent gel become turbid but nevertheless improves the stability of the metallogels. nmr, ft-ir and fluorescence spectroscopy show that the coordination interactions between the phosphonate groups of pcbp molecules and aluminum(iii) ions as well as the pi-pi interactions among pcbp molecules are involved during the gel formation process. (c) 2014 elsevier inc. all rights reserved.
收录类别SCI
语种英语
WOS记录号WOS:000335620500015
源URL[http://ir.ciac.jl.cn/handle/322003/57336]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Ding, Zicheng,Chen, Bo,Ding, Junqiao,et al. Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator[J]. journal of colloid and interface science,2014,425(1):102-109.
APA Ding, Zicheng,Chen, Bo,Ding, Junqiao,Wang,Lixiang,&Han,Yanchun.(2014).Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator.journal of colloid and interface science,425(1),102-109.
MLA Ding, Zicheng,et al."Supramolecular metallogels with complex of phosphonate substituted carbazole derivative and aluminum(III) ion as gelator".journal of colloid and interface science 425.1(2014):102-109.

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来源:长春应用化学研究所

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