Synergistic effect of activated carbon and Ni2O3 in promoting the thermal stability and flame retardancy of polypropylene
文献类型:期刊论文
作者 | Gong, Jiang ; Tian,Nana ; Liu,Jie ; Yao,Kun ; Jiang,Zhiwei ; Chen,Xuecheng ; Wen,Xin ; Mijowska,Ewa ; Tang,Tao |
刊名 | polymer degradation and stability |
出版日期 | 2014 |
卷号 | 99期号:5页码:18-26 |
关键词 | IMPROVING FIRE RETARDANCY CATALYZING CARBONIZATION NANOTUBE NANOCOMPOSITES FLAMMABILITY PROPERTIES CATALYTIC CARBONIZATION COMPOSITES COMBUSTION BEHAVIOR POLYMER SYSTEMS |
通讯作者 | liu,j |
英文摘要 | a novel combined catalyst of activated carbon (ac) with ni2o3 was demonstrated to be much more efficient than ac or ni2o3 alone in enhancing the char yield of polypropylene (pp) and improving its char layer structure, which greatly improved the thermal stability and flame retardancy of pp. the results of xray diffraction, field-emission scanning electron microscope and transmission electron microscope revealed that the residual char mainly consisted of carbon nanotubes (cnts). thermal gravimetric analyses results indicated that the combination of ac and ni2o3 dramatically enhanced the thermal stability of pp. the flame retardancy of pp and its composites was studied by cone calorimeter test. the heat release rate and total heat release of the ternary pp/7.5ac-7.5ni(2)o(3) composite decreased significantly in comparison with those of neat pp. the investigation of the synergetic mechanism showed that in the presence of both ac and ni2o3, a large amount of cnts were in situ formed from the degradation products of pp during combustion. this not only reduced the release of flammable degradation products of pp, but also acted as a thermal shield for energy feedback from the flame. in addition, the formation of a network-like structure of ac and ni2o3 particles in pp matrix favored the formation of a more compacted protective layer, which enhanced the flame retardancy of pp. (c) 2013 elsevier ltd. all rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-10-27 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57362] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Gong, Jiang,Tian,Nana,Liu,Jie,et al. Synergistic effect of activated carbon and Ni2O3 in promoting the thermal stability and flame retardancy of polypropylene[J]. polymer degradation and stability,2014,99(5):18-26. |
APA | Gong, Jiang.,Tian,Nana.,Liu,Jie.,Yao,Kun.,Jiang,Zhiwei.,...&Tang,Tao.(2014).Synergistic effect of activated carbon and Ni2O3 in promoting the thermal stability and flame retardancy of polypropylene.polymer degradation and stability,99(5),18-26. |
MLA | Gong, Jiang,et al."Synergistic effect of activated carbon and Ni2O3 in promoting the thermal stability and flame retardancy of polypropylene".polymer degradation and stability 99.5(2014):18-26. |
入库方式: OAI收割
来源:长春应用化学研究所
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