Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes
文献类型：期刊论文
| 作者 | Qu, Zhi ; Duan, Ranlong ; Pang, Xuan ; Gao,Bo ; Li,Xiang ; Tang,Zhaohui ; Wang,Xianhong ; Chen,Xuesi |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 52期号:9页码:1344-1352 |
| 关键词 | RING-OPENING POLYMERIZATION GROUP-3 METAL-COMPLEXES RACEMIC LACTIDE STEREOCOMPLEX FORMATION FERRIC ALKOXIDES INITIATOR MECHANISM KINETICS SALEN STEREOCHEMISTRY |
| 通讯作者 | pang,x |
| 英文摘要 | a series of bimetallic aluminum schiff-base complexes have been prepared and characterized. the complexes used as catalysts were applied in the lactide polymerization to test their activities and stereoselectivities. all polymerizations are living, as evidenced by the narrow polydispersities and the good fit between calculated and found number-average molecular weights of the isolated polymers. isotactic enriched polylactide was obtained by using these complexes. kinetic studies indicated that the polymerizations are both first-ordered with respect to lactide monomer and catalyst. (c) 2014 wiley periodicals, inc. j. polym. sci., part a: polym. chem. 2014, 52, 1344-1352 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57366]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qu, Zhi,Duan, Ranlong,Pang, Xuan,et al. Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes[J]. journal of polymer science part a-polymer chemistry,2014,52(9):1344-1352. |
| APA | Qu, Zhi.,Duan, Ranlong.,Pang, Xuan.,Gao,Bo.,Li,Xiang.,...&Chen,Xuesi.(2014).Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes.journal of polymer science part a-polymer chemistry,52(9),1344-1352. |
| MLA | Qu, Zhi,et al."Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes".journal of polymer science part a-polymer chemistry 52.9(2014):1344-1352. |
入库方式： OAI收割
来源：长春应用化学研究所
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