Orientation and surface activity of Janus particles at fluid-fluid interfaces
文献类型:期刊论文
作者 | Gao, Hui-Min ; Lu, Zhong-Yuan ; Liu, Hong ; Sun,Zhao-Yan ; An,Li-Jia |
刊名 | journal of chemical physics
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出版日期 | 2014 |
卷号 | 141期号:13页码:16806-16811 |
关键词 | OIL-WATER INTERFACE LIQUID-LIQUID INTERFACES MOLECULAR-DYNAMICS LIQUID/LIQUID INTERFACES UMBRELLA INTEGRATION COLLOIDAL PARTICLES COMPUTER-SIMULATION PICKERING EMULSIONS NANOPARTICLES COLLOIDOSOMES |
通讯作者 | gao,hm |
英文摘要 | we study the influence of shape of janus particles on their orientation and surface activity at fluid-fluid interfaces via molecular dynamics simulations. the janus particles are characterized by two regions with different wettability divided along their major axes. three types of janus particles are considered: janus spheres, janus rods, and janus disks. we find that janus spheres and janus rods prefer one orientation at the interface, regardless of the surface property. in contrast, janus disks can adopt one of two orientations when adhered to a fluid-fluid interface: one orientation corresponds to the equilibrium state and the other is a kinetically trapped metastable state. the orientation of janus disks strongly depends on the disk characteristics, such as their size, aspect ratio, and surface property. furthermore, we find that changes in the shape of janus particles strongly influence the interfacial tension at the fluid-fluid interface. according to the time evolution of the interfacial tension, the adsorption of janus particles is characterized by three adsorption stages based on different surface activities and adsorption kinetics depending on the particle shape. (c) 2014 aip publishing llc. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000343872800064 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57387] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Gao, Hui-Min,Lu, Zhong-Yuan,Liu, Hong,et al. Orientation and surface activity of Janus particles at fluid-fluid interfaces[J]. journal of chemical physics,2014,141(13):16806-16811. |
APA | Gao, Hui-Min,Lu, Zhong-Yuan,Liu, Hong,Sun,Zhao-Yan,&An,Li-Jia.(2014).Orientation and surface activity of Janus particles at fluid-fluid interfaces.journal of chemical physics,141(13),16806-16811. |
MLA | Gao, Hui-Min,et al."Orientation and surface activity of Janus particles at fluid-fluid interfaces".journal of chemical physics 141.13(2014):16806-16811. |
入库方式: OAI收割
来源:长春应用化学研究所
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