Photophysical properties and theoretical calculations of Cu(I) dendrimers
文献类型：期刊论文
| 作者 | Si, Zhenjun ; An, Chun-Ai ; Song, Shuyan ; Zhang,Hongjie |
| 刊名 | journal of luminescence
 |
| 出版日期 | 2014 |
| 卷号 | 148期号:22页码:103-110 |
| 关键词 | DENSITY-FUNCTIONAL THEORY EFFECTIVE CORE POTENTIALS EXCITED-STATES MOLECULAR CALCULATIONS COMPLEXES DENDRONS LIGANDS MODEL DNA |
| 通讯作者 | zhang,hj |
| 英文摘要 | the experimental and theoretical analyses on cu(i) dendrimers are essential for studying their photophysical properties and facilitating the applications of cu(i) complexes even though there are relatively few studies in it. therefore, we synthesize four cu(i) dendrimers cu-l1-cu-l4, the antenna effect is confirmed by the fact that the order of their luminescence quantum yield is cu-l1 < cu-l2 < cu-l3 < cu-l4. it is found that the 19,3';6',9 '']tercarbazole group narrows the energy gap between the homo and lumo of cu-l3 (cu-l4), which suggests that their photoluminescent spectra should red-shift compared with those of cu-l1 (cu-l2), but the experimental measurements prove that the excitation and emission spectra of cu-l3 (cu-l4) locate at the higher energy area in order to deeply understand their photophysical properties, their ground state geometry and absorption spectra are also theoretically simulated. (c) 2013 elsevier b.v. all rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57401]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Si, Zhenjun,An, Chun-Ai,Song, Shuyan,et al. Photophysical properties and theoretical calculations of Cu(I) dendrimers[J]. journal of luminescence,2014,148(22):103-110. |
| APA | Si, Zhenjun,An, Chun-Ai,Song, Shuyan,&Zhang,Hongjie.(2014).Photophysical properties and theoretical calculations of Cu(I) dendrimers.journal of luminescence,148(22),103-110. |
| MLA | Si, Zhenjun,et al."Photophysical properties and theoretical calculations of Cu(I) dendrimers".journal of luminescence 148.22(2014):103-110. |
入库方式： OAI收割
来源：长春应用化学研究所
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