Crystal structure, oxidation state and magnetism of SrxLa2-xCu0.5Ru0.5O4 (x=1, 1.5)
文献类型：期刊论文
| 作者 | Lu,Minfeng ; Deng,Xiaolong ; Waerenborgh,Joao C. ; Wu,Xiaojie ; Meng,Jian |
| 刊名 | journal of solid state chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 211期号:3页码:1-7 |
| 关键词 | HIGH-PRESSURE PHYSICAL-PROPERTIES CU LA2-XSRXCU1-YRUYO4-DELTA SUPERCONDUCTIVITY EVOLUTION BARUO3 OXIDES SYSTEM SR |
| 通讯作者 | lu,mf |
| 英文摘要 | srxla2-xcu0.5ru0.5o4 (x = 1, 1.5) oxides with k2nif4-type structure were prepared by solid state reaction and characterized by powder x-ray diffraction, x-ray photoelectron spectroscopy, magnetic and electrical resistivity measurements. the srlacu0.5ru0.5o4 phase was obtained for the first time with a negligible amount of impurities. the octahedral cu/ruo6 units are more elongated in srlacu0.5ru0.5o4 than in sr1.5la0.5cu0.5ru0.5o4 indicating a greater extent of static jahn-teller distortion. xps suggests that mixed ion pairs ru5+/ru4+ <-> cu+/cu2+ are present in srlacu0.5ru0.5o4, while ru remains as rus and cu as cu2+ in sr1.5la0.5cu0.5ru0.5o4. both samples show spin-glass behavior, which can be explained by competition between ferromagnetic and antiferromagnetic superexchange interactions. the negative weiss temperature estimated for srlacu0.5ru0.5o4, -318 k, is significantly lower than -11.5 k deduced for sr1.5la0.5cu0.5ru0.5o4 which may be related to the higher static jahn-teller distortion in the former oxide. (c) 2013 published by elsevier inc. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000331686400001 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57440]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu,Minfeng,Deng,Xiaolong,Waerenborgh,Joao C.,et al. Crystal structure, oxidation state and magnetism of SrxLa2-xCu0.5Ru0.5O4 (x=1, 1.5)[J]. journal of solid state chemistry,2014,211(3):1-7. |
| APA | Lu,Minfeng,Deng,Xiaolong,Waerenborgh,Joao C.,Wu,Xiaojie,&Meng,Jian.(2014).Crystal structure, oxidation state and magnetism of SrxLa2-xCu0.5Ru0.5O4 (x=1, 1.5).journal of solid state chemistry,211(3),1-7. |
| MLA | Lu,Minfeng,et al."Crystal structure, oxidation state and magnetism of SrxLa2-xCu0.5Ru0.5O4 (x=1, 1.5)".journal of solid state chemistry 211.3(2014):1-7. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。