Crystallization behaviors of KDP and ADP
文献类型：期刊论文
| 作者 | Sun,Congting ; Xue,Dongfeng |
| 刊名 | optical materials
 |
| 出版日期 | 2014 |
| 卷号 | 36期号:12页码:1966-1969 |
| 关键词 | SINGLE-CRYSTAL GROWTH CHEMICAL-BOND ZNO SUPERCAPACITANCE TRANSFORMATION MORPHOLOGY SIMULATION SAPPHIRE KH2PO4 KADP |
| 通讯作者 | xue,df |
| 英文摘要 | crystallographically, kdp and adp have familiar (h2po4-)(n) framework, which is formed via hydrogen bonding between h2po4- groups along main crystallographic axes. the common characteristics of both kdp and adp crystallization behaviours are studied from the viewpoint of (h2po4-)(n) framework. on the basis of chemical bonding theory of single crystal growth, the anisotropic hydrogen bonding in (h2po4-)(n) framework and the chemical bonding between k+/nh4+ and (h2po4-)(n) dominate the anisotropic thermodynamic equilibrium morphology of kdp and adp. the thermodynamic equilibrium morphology is used to find out the possible preferential growth directions for the dendrite growth of both kdp and adp, i.e., (100) and (101) directions. ir spectroscopy of both kdp and adp solutions with different concentrations has testified our theoretical results, which shows that h2po4-, ions are initially form (h2po4-)(n) framework, and then constituent cations inset into the (h2po4-)(n) framework during both kdp and adp crystallization processes. the present work can provide helpful basic information for the study of crystallization of mh2xo4 crystal family. (c) 2013 elsevier b.v. all rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57454]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun,Congting,Xue,Dongfeng. Crystallization behaviors of KDP and ADP[J]. optical materials,2014,36(12):1966-1969. |
| APA | Sun,Congting,&Xue,Dongfeng.(2014).Crystallization behaviors of KDP and ADP.optical materials,36(12),1966-1969. |
| MLA | Sun,Congting,et al."Crystallization behaviors of KDP and ADP".optical materials 36.12(2014):1966-1969. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。