Synthesis of star-like polybutadienes by a combination of living anionic polymerization and "click" coupling method
文献类型：期刊论文
| 作者 | Zhang, Guang-chun ; Zheng, Jun ; Liu, Feng ; Zhang,Zhi-jie ; Ma,Li ; Tang,Tao |
| 刊名 | 高分子科学(英文版) chinese journal of polymer science
 |
| 出版日期 | 2014 |
| 卷号 | 32期号:6页码:731-742 |
| 关键词 | DILUTE-SOLUTION PROPERTIES BRANCHED POLYMERS BLOCK-COPOLYMERS TERMINAL ALKYNES CHEMISTRY POLYSTYRENE TERPOLYMERS FUNCTIONALIZATION MACROMOLECULES POLYISOPRENES |
| 通讯作者 | tang,t |
| 英文摘要 | three-arm and four-arm star-like polybutadienes (pbds) were synthesized via the combination of living anionic polymerization and the click coupling method. kinetic study showed that the click reaction between the azido group terminated pbd-t-n-3 and the alkyne-containing multifunctional linking reagent was fast and highly efficient. all coupling reactions were fully accomplished within 40 min at 50 a degrees c in toluene in the presence of the reducing agent cu(0), proven by h-1-nmr, ftir and gpc measurements. for the coupling reactions between the pbd-t-n-3 polymer and dialkyne-containing compound, the final conversion of the coupled pbd-pbd polymer was ca. 97.0%. when a pbd-t-n-3 polymer was reacted with trialkyne-containing or tetraalkyne-containing compound, the conversion of three-arm or four-arm pbd was around 95.5% or 87.0%, respectively. several factors influencing the coupling efficiency were studied, including the molecular weight of the initial pbd-t-n-3, arm numbers and the molar ratio of the azido group to the alkynyl group. the results indicated that the conversion of the target products would be promoted when the molecular weight of the pbd-t-n-3 was low and the molar ratio of the azido to alkynyl groups was close to 1. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57465]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang, Guang-chun,Zheng, Jun,Liu, Feng,et al. Synthesis of star-like polybutadienes by a combination of living anionic polymerization and "click" coupling method[J]. 高分子科学(英文版) chinese journal of polymer science,2014,32(6):731-742. |
| APA | Zhang, Guang-chun,Zheng, Jun,Liu, Feng,Zhang,Zhi-jie,Ma,Li,&Tang,Tao.(2014).Synthesis of star-like polybutadienes by a combination of living anionic polymerization and "click" coupling method.高分子科学(英文版) chinese journal of polymer science,32(6),731-742. |
| MLA | Zhang, Guang-chun,et al."Synthesis of star-like polybutadienes by a combination of living anionic polymerization and "click" coupling method".高分子科学(英文版) chinese journal of polymer science 32.6(2014):731-742. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。