Efficient side-chain modification of dextran via base-catalyzed epoxide ring-opening and thiol-ene click chemistry in aqueous media
文献类型：期刊论文
| 作者 | Li, Ming-qiang ; Tang, Zhao-hui ; Wang, Chao ; Zhang,Yu ; Cui,Hai-tao ; Chen,Xue-si |
| 刊名 | 高分子科学(英文版) chinese journal of polymer science
 |
| 出版日期 | 2014 |
| 卷号 | 32期号:8页码:969-974 |
| 关键词 | IRON-OXIDE NANOPARTICLES CANCER-THERAPY GENE DELIVERY DOXORUBICIN HYDROGELS THERAPEUTICS CISPLATIN PLATFORM RELEASE SYSTEM |
| 通讯作者 | chen,xs |
| 英文摘要 | in this study, a novel approach by combining base-catalyzed epoxide ring-opening and thiol-ene click chemistry is presented for the side-chain modification of dextran. the vinyl-modified dextran is prepared by a basic epoxide ring opening reaction of allyl glycidyl ether in 0.1 mol/l naoh, followed by thiol-addition click reaction of three model sulfhydryl compounds using water-soluble irgacure 2959 as the photoinitiator, leading to side-chain functionalized dextran modified with carboxyl, bidentate dicarboxyl or amino groups. this is the first example of combining epoxide ring-opening and thiolene click chemistry for side-chain modification of dextran in aqueous media. importantly, it may also be extended as a convenient and efficient method for the side-chain modification of other polysaccharides. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57467]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li, Ming-qiang,Tang, Zhao-hui,Wang, Chao,et al. Efficient side-chain modification of dextran via base-catalyzed epoxide ring-opening and thiol-ene click chemistry in aqueous media[J]. 高分子科学(英文版) chinese journal of polymer science,2014,32(8):969-974. |
| APA | Li, Ming-qiang,Tang, Zhao-hui,Wang, Chao,Zhang,Yu,Cui,Hai-tao,&Chen,Xue-si.(2014).Efficient side-chain modification of dextran via base-catalyzed epoxide ring-opening and thiol-ene click chemistry in aqueous media.高分子科学(英文版) chinese journal of polymer science,32(8),969-974. |
| MLA | Li, Ming-qiang,et al."Efficient side-chain modification of dextran via base-catalyzed epoxide ring-opening and thiol-ene click chemistry in aqueous media".高分子科学(英文版) chinese journal of polymer science 32.8(2014):969-974. |
入库方式： OAI收割
来源：长春应用化学研究所
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