Growth mechanism of liquid Hg/solid beta-HgS metal-semiconductor heterostructures
文献类型：期刊论文
| 作者 | Zhang, Xugang ; Niu, Li ; Tang, Zhiyong |
| 刊名 | 科学通报(英文版) chinese science bulletin
 |
| 出版日期 | 2014 |
| 卷号 | 59期号:-30页码:3894-3903 |
| 关键词 | X-RAY-DIFFRACTION SELECTIVE GROWTH L-CYSTEINE NANOWIRES COMPLEXES MERCURY TIPS ZNS |
| 通讯作者 | niu,l |
| 英文摘要 | density functional theory (dft) was utilized to simulate the reactions occurred in the mixture solution of cysteine and hg(ii) ions with the ratio < 2. simulation result shows that hg ions will coordinate to cysteine by the thiol groups with the form of s-hg-2 and s-hg-3, and moreover, the content of free hg ions can only be reduced by these two forms. oh- plays an important role in the growth of beta-hgs, because its nucleophilic substitution reaction supplies plenty of hg-s-hg radicals, which will be adsorbed onto the surface of liquid mercury ball and form the precursor of beta-hgs(111) plane. three valent bonds adsorption of hg-s-hg radicals onto the surface of hg ball has more adsorption energy (-32.768 kcal mol(-1)) than that of two valent bond adsorption (-20.882 kcal mol(-1)). hg balls will stop growing after completely covered with hg-s-hg radicals and their size will be limited. the growth direction of beta-hgs is parallel to the "repelling" force, that is [111] direction in beta-hgs lattice. the calculated results are in good agreement with the experimental observations, demonstrating that the dft method can be taken as a very useful tool to interpret the solution reactions that cannot be solved by conventional methods. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57508]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang, Xugang,Niu, Li,Tang, Zhiyong. Growth mechanism of liquid Hg/solid beta-HgS metal-semiconductor heterostructures[J]. 科学通报(英文版) chinese science bulletin,2014,59(-30):3894-3903. |
| APA | Zhang, Xugang,Niu, Li,&Tang, Zhiyong.(2014).Growth mechanism of liquid Hg/solid beta-HgS metal-semiconductor heterostructures.科学通报(英文版) chinese science bulletin,59(-30),3894-3903. |
| MLA | Zhang, Xugang,et al."Growth mechanism of liquid Hg/solid beta-HgS metal-semiconductor heterostructures".科学通报(英文版) chinese science bulletin 59.-30(2014):3894-3903. |
入库方式： OAI收割
来源：长春应用化学研究所
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