EQCM Studies on the Effect of Anti-freezing Additives on the Storage Behavior of Ions at Activated Carbon Electrodes in NaClO4 Aqueous Solutions
文献类型:期刊论文
作者 | Gao Jichao ; Qi Li ; Wang Hongyu |
刊名 | 高等学校化学学报 chemical journal of chinese universities-chinese
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出版日期 | 2014 |
卷号 | 35期号:3页码:608-612 |
关键词 | PROPYLENE CARBONATE ELECTROLYTES |
通讯作者 | wang,hd |
英文摘要 | electrochemical quartz crystal microbalance(eqcm) was used to investigate the adsorption of na+ into the micropores of activated carbon in 5 mol/l naclo4 +x mol/l meoh and 5 mol/l naclo4 +x mol/l etoh aqueous solutions. molecule numbers of methanol or ethanol associated with each na+ at the interfaces were estimated. the results show that methanol and ethanol are adsorbed into the micropores together with na+ the higher the concentration of methanol and ethanol in bulk solutions was, the more molecule numbers of methanol or ethanol associated with each na+ adsorpted into the pores of activated carbon; methanol and ethanol adsorpted into the pores occupied some space of the micropores and lowered the dielectric constant of the double layers, thus suppressed the specific capacitance of maxsorb negative electrodes. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000333550300026 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57535] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Gao Jichao,Qi Li,Wang Hongyu. EQCM Studies on the Effect of Anti-freezing Additives on the Storage Behavior of Ions at Activated Carbon Electrodes in NaClO4 Aqueous Solutions[J]. 高等学校化学学报 chemical journal of chinese universities-chinese,2014,35(3):608-612. |
APA | Gao Jichao,Qi Li,&Wang Hongyu.(2014).EQCM Studies on the Effect of Anti-freezing Additives on the Storage Behavior of Ions at Activated Carbon Electrodes in NaClO4 Aqueous Solutions.高等学校化学学报 chemical journal of chinese universities-chinese,35(3),608-612. |
MLA | Gao Jichao,et al."EQCM Studies on the Effect of Anti-freezing Additives on the Storage Behavior of Ions at Activated Carbon Electrodes in NaClO4 Aqueous Solutions".高等学校化学学报 chemical journal of chinese universities-chinese 35.3(2014):608-612. |
入库方式: OAI收割
来源:长春应用化学研究所
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