Aluminum Schiff Base Catalyst for Ring-opening Polymerization of epsilon-Caprolactone
文献类型：期刊论文
| 作者 | Qu Zhi ; Li Xiang ; Pang Xuan ; Duan,Ranlong ; Gao,Bo ; Chen,Xuesi |
| 刊名 | 高等学校化学学报 chemical journal of chinese universities-chinese
 |
| 出版日期 | 2014 |
| 卷号 | 35期号:4页码:869-872 |
| 关键词 | CYCLIC ESTERS STEREOSELECTIVE POLYMERIZATION PROPYLENE-OXIDE COMPLEXES LACTIDES LIGANDS SPECTROSCOPY MECHANISM COPOLYMER SINGLE |
| 通讯作者 | chen,xs |
| 英文摘要 | the catalysts with high activity and low toxicity for ring opening polymerization(rop) of epsilon-caprolactone had drawn much attention both in academia and industry. a series of asymmetric schiff base aluminum complexes containing ligands that differed in their steric properties were synthesized. their catalytic properties in the solution polymerization of epsilon-cl were examined. the kinetics studies of all complexes/2-propanol indicated that all of polymerizations were first-ordered reaction to monomers, and the polymerization rate of electrophilic substituted complex was about 4 times the non-electrophilic substituted complex in rop of epsilon-cl. the results evaluated that the electrophilic substituent of ligands ha great influence on the catalytic activity of the complex. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000334986100031 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57537]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qu Zhi,Li Xiang,Pang Xuan,et al. Aluminum Schiff Base Catalyst for Ring-opening Polymerization of epsilon-Caprolactone[J]. 高等学校化学学报 chemical journal of chinese universities-chinese,2014,35(4):869-872. |
| APA | Qu Zhi,Li Xiang,Pang Xuan,Duan,Ranlong,Gao,Bo,&Chen,Xuesi.(2014).Aluminum Schiff Base Catalyst for Ring-opening Polymerization of epsilon-Caprolactone.高等学校化学学报 chemical journal of chinese universities-chinese,35(4),869-872. |
| MLA | Qu Zhi,et al."Aluminum Schiff Base Catalyst for Ring-opening Polymerization of epsilon-Caprolactone".高等学校化学学报 chemical journal of chinese universities-chinese 35.4(2014):869-872. |
入库方式： OAI收割
来源：长春应用化学研究所
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