Monte Carlo Simulation of the Shear Effects on the Sol-gel Transition of Block Copolymers in Solution
文献类型：期刊论文
| 作者 | Li Liangyi ; Li Zhanwei ; Fu Cuiliu ; Sun,Zhaoyan ; An,Lijia ; Sun,Yanbo |
| 刊名 | 高等学校化学学报 chemical journal of chinese universities-chinese
 |
| 出版日期 | 2014 |
| 卷号 | 35期号:5页码:1068-1074 |
| 关键词 | ABA TRIBLOCK COPOLYMER ASSOCIATIVE POLYMERS SELECTIVE SOLVENT RHEOLOGICAL PROPERTIES DYNAMICS GELATION MELTS MODEL FLOW |
| 通讯作者 | sun,zy |
| 英文摘要 | by using nonequilibrium monte carlo simulation approach, the shearing effects on the sol-gel transition of aba telechelic triblock copolymers in a b block selective solvent were investigated. the simulation results show that the shear makes the sol-gel transition concentration area shifting to lower concentrations. microscopic structure properties of the solution under shearing were simulated, such as the fractions of chains with different conformations, micelle aggregation number and micelle number, cluster aggregation number and cluster number, average size of a single chain and the stretching degree of chains. the shear makes polymer chains stretched, so telechelic chains have more opportunity to form bridge conformation, which might be the reason why a certain extent shear promotes the sol-gel transition process. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/57539]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li Liangyi,Li Zhanwei,Fu Cuiliu,et al. Monte Carlo Simulation of the Shear Effects on the Sol-gel Transition of Block Copolymers in Solution[J]. 高等学校化学学报 chemical journal of chinese universities-chinese,2014,35(5):1068-1074. |
| APA | Li Liangyi,Li Zhanwei,Fu Cuiliu,Sun,Zhaoyan,An,Lijia,&Sun,Yanbo.(2014).Monte Carlo Simulation of the Shear Effects on the Sol-gel Transition of Block Copolymers in Solution.高等学校化学学报 chemical journal of chinese universities-chinese,35(5),1068-1074. |
| MLA | Li Liangyi,et al."Monte Carlo Simulation of the Shear Effects on the Sol-gel Transition of Block Copolymers in Solution".高等学校化学学报 chemical journal of chinese universities-chinese 35.5(2014):1068-1074. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。