中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates

文献类型:期刊论文

作者Li, Hui-Jing1,2,3; Wang, Rui1; Gao, Jing1; Wang, Yuan-Yuan1; Luo, Dong-Hui1; Wu, Yan-Chao1
刊名ADVANCED SYNTHESIS & CATALYSIS
出版日期2015-05-04
卷号357期号:7页码:1393-1397
关键词benzyl alcohols bismuth selectivity substitution sulfonates
英文摘要A bismuth(III) bromide-catalysed direct substitution of benzyl alcohols with arylsulfonylmethyl isocyanides affords sulfinates under mild acidic conditions. An unforeseen reversed reactivity was observed in this highly selective formation of sulfinates instead of the formation of the usually favoured sulfones. Cytotoxicity tests (in vitro) indicated that the sulfinates exhibit antibiotic activity against a human leukaemia cell line HL-60, which would widen the structural diversity of this antitumour target and confirm the perspectives of further investigations.
收录类别SCI
语种英语
公开日期2015-11-02
源URL[http://ir.iccas.ac.cn/handle/121111/28008]  
专题化学研究所_分子识别与功能实验室
作者单位1.Harbin Inst Technol, Sch Marine Sci & Technol, Weihai 264209, Shandong, Peoples R China
2.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Li, Hui-Jing,Wang, Rui,Gao, Jing,et al. Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates[J]. ADVANCED SYNTHESIS & CATALYSIS,2015,357(7):1393-1397.
APA Li, Hui-Jing,Wang, Rui,Gao, Jing,Wang, Yuan-Yuan,Luo, Dong-Hui,&Wu, Yan-Chao.(2015).Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates.ADVANCED SYNTHESIS & CATALYSIS,357(7),1393-1397.
MLA Li, Hui-Jing,et al."Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates".ADVANCED SYNTHESIS & CATALYSIS 357.7(2015):1393-1397.

入库方式: OAI收割

来源:化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。