Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates
文献类型：期刊论文
| 作者 | Li, Hui-Jing1,2,3; Wang, Rui1; Gao, Jing1; Wang, Yuan-Yuan1; Luo, Dong-Hui1; Wu, Yan-Chao1 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2015-05-04 |
| 卷号 | 357期号:7页码:1393-1397 |
| 关键词 | benzyl alcohols bismuth selectivity substitution sulfonates |
| 英文摘要 | A bismuth(III) bromide-catalysed direct substitution of benzyl alcohols with arylsulfonylmethyl isocyanides affords sulfinates under mild acidic conditions. An unforeseen reversed reactivity was observed in this highly selective formation of sulfinates instead of the formation of the usually favoured sulfones. Cytotoxicity tests (in vitro) indicated that the sulfinates exhibit antibiotic activity against a human leukaemia cell line HL-60, which would widen the structural diversity of this antitumour target and confirm the perspectives of further investigations. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-02 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28008]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Harbin Inst Technol, Sch Marine Sci & Technol, Weihai 264209, Shandong, Peoples R China 2.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hui-Jing,Wang, Rui,Gao, Jing,et al. Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates[J]. ADVANCED SYNTHESIS & CATALYSIS,2015,357(7):1393-1397. |
| APA | Li, Hui-Jing,Wang, Rui,Gao, Jing,Wang, Yuan-Yuan,Luo, Dong-Hui,&Wu, Yan-Chao.(2015).Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates.ADVANCED SYNTHESIS & CATALYSIS,357(7),1393-1397. |
| MLA | Li, Hui-Jing,et al."Bismuth(III) Bromide-Catalysed Substitution of Benzyl Alcohols with Arylsulfonylmethyl Isocyanides: An Unexpected Access to Sulfinates".ADVANCED SYNTHESIS & CATALYSIS 357.7(2015):1393-1397. |
入库方式： OAI收割
来源：化学研究所
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