A method for cyclic and tadpole-shaped polymers
文献类型：期刊论文
| 作者 | Tang, Qingquan; Zhang, Ke |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2015-08-01 |
| 卷号 | 64期号:8页码:1060-1065 |
| 关键词 | cyclic polymer tadpole-shaped polymer reversible addition-fragmentation chain transfer polymerization bromomaleimide-thiol substitution reaction |
| 英文摘要 | Reversible addition-fragmentation chain transfer polymerization (RAFT) was used to produce well-defined telechelic poly(N-isopropylacrylamide) (PNIPAM) with dibromomaleimide and dithiobenzoate groups at each end of the polymer chain by virtue of the functional RAFT agent 3,4-dibromo-1-(4-cyano-4-(phenylcarbonothioylthio)pentanoic)-2,5-dihydro-1H-pyrrole-2,5-dione. Cyclic PNIPAM was then obtained using an in situ intramolecular bromomaleimide-thiol substitution reaction after NaBH4 reduction of the dithiobenzoate end group to release a thiol group. In this ring-closure process, another bromo substituent on the maleimide group survived, being a single reactive site for post-functionalizing the cyclic PNIPAM by a second bromomaleimide-thiol substitution reaction. After being reacted with 2-aminoethanethiol, the resultant amino-functionalized cyclic PNIPAM was further demonstrated as a building block to construct a tadpole-shaped block copolymer by coupling with linear succinimidyl ester end-functionalized poly(ethylene oxide) based on active ester click chemistry. (c) 2015 Society of Chemical Industry |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-02 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27937]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Qingquan,Zhang, Ke. A method for cyclic and tadpole-shaped polymers[J]. POLYMER INTERNATIONAL,2015,64(8):1060-1065. |
| APA | Tang, Qingquan,&Zhang, Ke.(2015).A method for cyclic and tadpole-shaped polymers.POLYMER INTERNATIONAL,64(8),1060-1065. |
| MLA | Tang, Qingquan,et al."A method for cyclic and tadpole-shaped polymers".POLYMER INTERNATIONAL 64.8(2015):1060-1065. |
入库方式： OAI收割
来源：化学研究所
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