中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization

文献类型:期刊论文

作者Sun, Peng1; Yan, Guowei1; Tang, Qingquan1; Chen, Yongming1,2; Zhang, Ke1
刊名POLYMER
出版日期2015-05-01
卷号64页码:202-209
关键词Atom transfer radical polymerization UV-induced bioorthogonal click chemistry Reactive polymer
英文摘要Two functional atom transfer radical polymerization (ATRP) initiators (I-2 and I-3) were developed bearing a cyclopropenone-masked dibenzocyclooctyne group. ATRP was then explored on three main kinds of monomers for radical polymerization including acrylates, styrenics, and methacrylates based on these novel initiators. By a standard ATRP protocol, the polymerization behavior demonstrated the living characteristics for all three cases and the corresponding well-defined cyclopropenone-masked dibenzocyclooctyne end or middle functionalized polymers were produced conveniently. Since UV irradiation of the cyclopropenone-masked dibenzocyclooctynes could quantitatively release the dibenzocyclooctynes widely used in strain promoted azide-alkyne cycloaddition bioorthogonal click reaction, these novel ATRP initiators and the resultant well-defined polymers should play an important role in the preparation of topological polymers and bio-synthetic polymer conjugates and many other related fields. (C) 2014 Elsevier Ltd. All rights reserved.
收录类别SCI
语种英语
公开日期2015-11-02
源URL[http://ir.iccas.ac.cn/handle/121111/28113]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Sun Yat Sen Univ, Sch Chem & Chem Engn, Key Lab Polymer Composite & Funct Mat, Minist Educ, Guangzhou 510275, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Sun, Peng,Yan, Guowei,Tang, Qingquan,et al. Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization[J]. POLYMER,2015,64:202-209.
APA Sun, Peng,Yan, Guowei,Tang, Qingquan,Chen, Yongming,&Zhang, Ke.(2015).Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization.POLYMER,64,202-209.
MLA Sun, Peng,et al."Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization".POLYMER 64(2015):202-209.

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来源:化学研究所

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