Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization
文献类型：期刊论文
| 作者 | Sun, Peng1; Yan, Guowei1; Tang, Qingquan1; Chen, Yongming1,2; Zhang, Ke1 |
| 刊名 | POLYMER
 |
| 出版日期 | 2015-05-01 |
| 卷号 | 64页码:202-209 |
| 关键词 | Atom transfer radical polymerization UV-induced bioorthogonal click chemistry Reactive polymer |
| 英文摘要 | Two functional atom transfer radical polymerization (ATRP) initiators (I-2 and I-3) were developed bearing a cyclopropenone-masked dibenzocyclooctyne group. ATRP was then explored on three main kinds of monomers for radical polymerization including acrylates, styrenics, and methacrylates based on these novel initiators. By a standard ATRP protocol, the polymerization behavior demonstrated the living characteristics for all three cases and the corresponding well-defined cyclopropenone-masked dibenzocyclooctyne end or middle functionalized polymers were produced conveniently. Since UV irradiation of the cyclopropenone-masked dibenzocyclooctynes could quantitatively release the dibenzocyclooctynes widely used in strain promoted azide-alkyne cycloaddition bioorthogonal click reaction, these novel ATRP initiators and the resultant well-defined polymers should play an important role in the preparation of topological polymers and bio-synthetic polymer conjugates and many other related fields. (C) 2014 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-02 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28113]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Sun Yat Sen Univ, Sch Chem & Chem Engn, Key Lab Polymer Composite & Funct Mat, Minist Educ, Guangzhou 510275, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Peng,Yan, Guowei,Tang, Qingquan,et al. Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization[J]. POLYMER,2015,64:202-209. |
| APA | Sun, Peng,Yan, Guowei,Tang, Qingquan,Chen, Yongming,&Zhang, Ke.(2015).Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization.POLYMER,64,202-209. |
| MLA | Sun, Peng,et al."Well-defined cyclopropenone-masked dibenzocyclooctyne functionalized polymers from atom transfer radical polymerization".POLYMER 64(2015):202-209. |
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来源：化学研究所
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