Intelligent rubber with tailored properties for self-healing and shape memory
文献类型：期刊论文
| 作者 | Wang, Dong1,2; Guo, Jing1,2; Zhang, Huan1,2; Cheng, Beichen1; Shen, Heng1,2; Zhao, Ning1; Xu, Jian1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2015 |
| 卷号 | 3期号:24页码:12864-12872 |
| 英文摘要 | A strategy for combining covalent and non-covalent cross-links to construct multifunctional rubber materials with intelligent self-healing and shape memory ability is demonstrated. Rubbers were prepared by self-assembly of complementary polybutadiene oligomers bearing carboxylic acid and amine groups through reversible ionic hydrogen bonds via the acid-base reaction, and then further covalently crosslinked by tri-functional thiol via the thiol-ene reaction. The resulting polymers exhibit self-healing and shape memory functions owing to the reversible ionic hydrogen bonds. The covalent cross-linking density can be tuned to achieve tailorable mechanical and stimuli-responsive properties: a low covalent cross-linking density maintains the remarkable self-healing capability of rubber at ambient temperature without any external stimulus, while a high covalent cross-linking density improves the mechanical strength and induces shape memory behavior, but effective self-healing needs to be triggered at high temperature. This strategy might open a promising pathway to fabricate intelligent multifunctional polymers with versatile functions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-02 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28184]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Dong,Guo, Jing,Zhang, Huan,et al. Intelligent rubber with tailored properties for self-healing and shape memory[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(24):12864-12872. |
| APA | Wang, Dong.,Guo, Jing.,Zhang, Huan.,Cheng, Beichen.,Shen, Heng.,...&Xu, Jian.(2015).Intelligent rubber with tailored properties for self-healing and shape memory.JOURNAL OF MATERIALS CHEMISTRY A,3(24),12864-12872. |
| MLA | Wang, Dong,et al."Intelligent rubber with tailored properties for self-healing and shape memory".JOURNAL OF MATERIALS CHEMISTRY A 3.24(2015):12864-12872. |
入库方式： OAI收割
来源：化学研究所
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