Enhanced electroactive and mechanical properties of poly(vinylidene fluoride) by controlling crystallization and interfacial interactions with low loading polydopamine coated BaTiO3
文献类型：期刊论文
| 作者 | Jia, Nan1; Xing, Qian1; Liu, Xu1; Sun, Jing2; Xia, Guangmei3; Huang, Wei4; Song, Rui1 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2015-09-01 |
| 卷号 | 453页码:169-176 |
| 关键词 | Poly(vinylidene fluoride) Polydopamine Barium titanate Interfacial interaction Piezoelectric materials |
| 英文摘要 | Poly(vinylidene fluoride) (PVDF) is a semi-crystalline polymer and the polar beta-phase of PVDF shows superb electroactive properties. In order to enhance the beta-phase of PVDF, extreme low content of BaTiO3 nanoparticles (BT-NPs) coated with polydopamine (Pdop) were incorporated into PVDF matrix by solution casting. The beta-phase of the resulting PVDF nanocomposites film was dramatically increased and the d(33) value reached 34.3 +/- 0.4 pCN(-1). It is found that the Pdop layer could improve the dispersibility and stability of the BT NPs in solution and endow the BT NPs good dispersity in the PVDF matrix. Moreover, the interfacial interaction between PVDF chains and the surface of BT-Pdop nanoparticles (BT-Pdop NPs) were revealed, in which the CF2 groups on PVDF could interact with the electron-rich plane of aromatic ring of Pdop moiety. This interaction, led to the increase of the crystallization activation energy as derived from the DSC nonisothermal crystallization measurement. The alpha-beta crystal transformation, organization of interfacial interactions as well as the prevention of agglomeration of BT-NPs confer the improvement of mechanical and thermal properties of PVDF, such as toughness, tensile strength, elongation at break, and thermal conductivity. 2015 Elsevier Inc. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-02 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27989]  |
| 专题 | 化学研究所_高技术材料实验室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, Shanghai 200050, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Nan,Xing, Qian,Liu, Xu,et al. Enhanced electroactive and mechanical properties of poly(vinylidene fluoride) by controlling crystallization and interfacial interactions with low loading polydopamine coated BaTiO3[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2015,453:169-176. |
| APA | Jia, Nan.,Xing, Qian.,Liu, Xu.,Sun, Jing.,Xia, Guangmei.,...&Song, Rui.(2015).Enhanced electroactive and mechanical properties of poly(vinylidene fluoride) by controlling crystallization and interfacial interactions with low loading polydopamine coated BaTiO3.JOURNAL OF COLLOID AND INTERFACE SCIENCE,453,169-176. |
| MLA | Jia, Nan,et al."Enhanced electroactive and mechanical properties of poly(vinylidene fluoride) by controlling crystallization and interfacial interactions with low loading polydopamine coated BaTiO3".JOURNAL OF COLLOID AND INTERFACE SCIENCE 453(2015):169-176. |
入库方式： OAI收割
来源：化学研究所
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