Nickel(II) Complexes Bearing 4-Arylimino-1,2,3-trihydroacridines: Synthesis, Characterization, and Ethylene Oligomerization
文献类型：期刊论文
| 作者 | Wang, Shengdong1,2,3,4; Du, Shizhen; Zhang, Wenjuan3,4; Asuha, Sin1,2; Sun, Wen-Hua3,4
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| 刊名 | CHEMISTRYOPEN
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| 出版日期 | 2015-06-01 |
| 卷号 | 4期号:3页码:328-334 |
| 关键词 | 4-arylimino-1 catalysts ethylene nickel(II) complexes oligomerization 2 3-trihydroacridines |
| 英文摘要 | Nickel(II) complexes have attracted much attention as a new generation of olefin catalysts since the alpha-diiminonickel complex was discovered as a highly efficient procatalyst for ethylene polymerization. A series of novel 4-arylimino-1,2,3-trihydroacridylnickel(II) dihalide complexes was synthesized in a one-pot reaction of 2,3-dihydroacridine-4-one and different anilines with nickel(II) chloride or nickel(II) bromide 1,2-dimethoxyethane complex. The complexes were characterized by infrared spectroscopy and elemental analysis. The molecular structures of the representative complexes 4-(2,6-diisopropylphenylimino)-1,2,3-trihydroacridylnickel(II) dichloride (C3), 4-(2,4,6-trimethylphenylimino)-1,2,3-trihydroacridylnickel dichloride(II) (C4), and 4-(2,4,6-trimethylphenylimino)-1,2,3-trihydroacridylnickel(II) dibromide (C9) were confirmed by single-crystal X-ray crystallography, revealing a distorted tetrahedral geometry around the nickel(II) of C3 and distorted trigonal bipyramidal geometry for C4 and C9. With the activation of trimethyl-aluminium (TMA), all nickel(II) complexes exhibited good activity for ethylene oligomerization, and oligomer products ranged from butene (C-4) to hexadecene (C-16). |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-02 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27945]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Inner Mongolia Normal Univ, Chem & Environm Sci Coll, Hohhot 010022, Peoples R China 2.Key Lab Phys & Chem Funct Mat Inner Mongolia, Hohhot 010022, Peoples R China 3.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Shengdong,Du, Shizhen,Zhang, Wenjuan,et al. Nickel(II) Complexes Bearing 4-Arylimino-1,2,3-trihydroacridines: Synthesis, Characterization, and Ethylene Oligomerization[J]. CHEMISTRYOPEN,2015,4(3):328-334. |
| APA | Wang, Shengdong,Du, Shizhen,Zhang, Wenjuan,Asuha, Sin,&Sun, Wen-Hua.(2015).Nickel(II) Complexes Bearing 4-Arylimino-1,2,3-trihydroacridines: Synthesis, Characterization, and Ethylene Oligomerization.CHEMISTRYOPEN,4(3),328-334. |
| MLA | Wang, Shengdong,et al."Nickel(II) Complexes Bearing 4-Arylimino-1,2,3-trihydroacridines: Synthesis, Characterization, and Ethylene Oligomerization".CHEMISTRYOPEN 4.3(2015):328-334. |
入库方式： OAI收割
来源：化学研究所
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