Comonomer-Induced Stereo-Selectivity Enhancement in a C-2-Symmetric Metallocene-Catalyzed Propylene Polymerization
文献类型：期刊论文
| 作者 | Ma, Lin1,2; Dong, Jin-Yong1 |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2015-04-01 |
| 卷号 | 36期号:8页码:733-738 |
| 关键词 | copolymerization C-2-symmetric metallocene catalysts propylene stereo-selectivity trans trans cis-1 5 9-cyclododecatriene |
| 英文摘要 | Propylene polymerization is carried out with a C-2-symmetric metallocene catalyst of rac Et(Ind)(2)ZrCl2/MAO at 40 degrees C in the presence of a cyclo-triene of trans, trans, cis-1,5,9-cyclododecatriene ((E, E, Z)-CDT). Comonomer incorporations are rather low (<0.10 mol%). However, it is shown for the first time that the comonomer causes a noticeable increase in poly propylene isotacticity (>7% in [mmmm]). (E, E, Z)-CDT is speculated to coordinate to the metal center forming comonomer-complexed active sites in charge of the entire polymerization reaction with decreased activity however increased propylene enantiomorphic selectivity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-02 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28010]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Lin,Dong, Jin-Yong. Comonomer-Induced Stereo-Selectivity Enhancement in a C-2-Symmetric Metallocene-Catalyzed Propylene Polymerization[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2015,36(8):733-738. |
| APA | Ma, Lin,&Dong, Jin-Yong.(2015).Comonomer-Induced Stereo-Selectivity Enhancement in a C-2-Symmetric Metallocene-Catalyzed Propylene Polymerization.MACROMOLECULAR RAPID COMMUNICATIONS,36(8),733-738. |
| MLA | Ma, Lin,et al."Comonomer-Induced Stereo-Selectivity Enhancement in a C-2-Symmetric Metallocene-Catalyzed Propylene Polymerization".MACROMOLECULAR RAPID COMMUNICATIONS 36.8(2015):733-738. |
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来源：化学研究所
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