Remote Chiral Communication in Coadsorber-Induced Enantioselective 2D Supramolecular Assembly at a Liquid/Solid Interface
文献类型：期刊论文
| 作者 | Chen, Ting1,2; Li, Shu-Ying1,2,3; Wang, Dong1,2; Yao, Man4; Wan, Li-Jun1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2015-03-27 |
| 卷号 | 54期号:14页码:4309-4314 |
| 关键词 | chiral communication interfaces scanning tunneling microscopy supramolecular assembly surface chirality |
| 英文摘要 | Remote chiral communication in 2D supramolecular assembly at a liquid/solid interface was investigated at the molecular level. The stereochemical information in a chiral coadsorber was transmitted over a flexible spacer with a length of up to five methylene groups to a 2D supramolecular assembly of achiral building blocks with the cooperation of specific hydrogen bonding between the chiral coadsorber and achiral building blocks and the confinement effect during 2D crystallization. When the position of the stereogenic center was changed with respect to the stereocontrolling moiety, an odd-even effect was found. A stereogenic center closer to the stereocontrolling moiety transmitted the stereochemical information to the 2D supramolecular assembly more reliably. This result is beneficial not only for mechanistic understanding of chiral communication in 2D supramolecular assembly on surfaces but also for the rational design of homochiral supramolecular assemblies on surfaces. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28492]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China 4.Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Ting,Li, Shu-Ying,Wang, Dong,et al. Remote Chiral Communication in Coadsorber-Induced Enantioselective 2D Supramolecular Assembly at a Liquid/Solid Interface[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(14):4309-4314. |
| APA | Chen, Ting,Li, Shu-Ying,Wang, Dong,Yao, Man,&Wan, Li-Jun.(2015).Remote Chiral Communication in Coadsorber-Induced Enantioselective 2D Supramolecular Assembly at a Liquid/Solid Interface.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(14),4309-4314. |
| MLA | Chen, Ting,et al."Remote Chiral Communication in Coadsorber-Induced Enantioselective 2D Supramolecular Assembly at a Liquid/Solid Interface".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.14(2015):4309-4314. |
入库方式： OAI收割
来源：化学研究所
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