Unique post-functionalization method for ROMP polymers based on Triazolinedione Alder-ene chemistry
文献类型：期刊论文
| 作者 | Zhao, Yuming; Chen, Jiqiang; Zhu, Wen; Zhang, Ke |
| 刊名 | POLYMER
 |
| 出版日期 | 2015-09-15 |
| 卷号 | 74页码:16-20 |
| 关键词 | Triazolinedione based Alder-ene reaction Living ring-opening metathesis polymerization Post-functionalization |
| 英文摘要 | Triazolinedione (TAD) based Alder-ene reaction was demonstrated as a unique method to efficiently post-functionalize the well-defined polymers derived from living ring-opening metathesis polymerization (ROMP). Using 4-nitrophenyl-1,2,4-triazoline-3,5-dione (p-NO2-PhTAD) as a model TAD compound to react with the double bonds in the backbone of ROMP polymers, the model polymer of poly(N-propyl-5-norbornene-exo-2,3-dicarboximide) (Poly-1) was successfully post-functionalized by grafting the p-NO2-PhTAD functional groups onto the polymer backbone. The TAD based Alder-ene post-functionalization reaction and the resultant p-NO2-PhTAD functionalized Poly-1 were systematically investigated by nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). In addition, using a difunctional TAD of 4,40( 4,4'-diphenylmethylene)-bis-(1,2,4-triazoline-3,5-dione) as a model crosslinking agent, network materials were efficiently produced by crosslinking ROMP derived Poly-1 from TAD based Alder-ene chemistry. (C) 2015 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28410]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Yuming,Chen, Jiqiang,Zhu, Wen,et al. Unique post-functionalization method for ROMP polymers based on Triazolinedione Alder-ene chemistry[J]. POLYMER,2015,74:16-20. |
| APA | Zhao, Yuming,Chen, Jiqiang,Zhu, Wen,&Zhang, Ke.(2015).Unique post-functionalization method for ROMP polymers based on Triazolinedione Alder-ene chemistry.POLYMER,74,16-20. |
| MLA | Zhao, Yuming,et al."Unique post-functionalization method for ROMP polymers based on Triazolinedione Alder-ene chemistry".POLYMER 74(2015):16-20. |
入库方式： OAI收割
来源：化学研究所
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