Intramolecular charge-transfer emission from conjugated polymer nanoparticles: the terminal group effect on electronic and optical properties
文献类型：期刊论文
| 作者 | Wu, Xiaofu1; Li, Haibo2; Xu, Yuxiang2; Tong, Hui1; Wang, Lixiang1 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:12页码:2305-2311 |
| 英文摘要 | Tuning fluorescence properties and frontier orbital energy levels of hyperbranched conjugated polymer nanoparticles (HCPN-NMe) by the facile introduction of terminal N,N-dimethylaniline groups via an intramolecular charge transfer (ICT) process between the nanoparticle core and the terminal groups was demonstrated for the first time. Compared with the similar hyperbranched conjugated polymer nanoparticles with terminal benzene groups (HCPN-H), a large Stokes shift and remarkable fluorescence solvatochromism were observed for HCPN-NMe. Based on the environmental-sensitive ICT emission, HCPN-NMe can be used as a fluorescence sensor for the detection of water in THF with enhanced sensitivity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28434]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Xiaofu,Li, Haibo,Xu, Yuxiang,et al. Intramolecular charge-transfer emission from conjugated polymer nanoparticles: the terminal group effect on electronic and optical properties[J]. POLYMER CHEMISTRY,2015,6(12):2305-2311. |
| APA | Wu, Xiaofu,Li, Haibo,Xu, Yuxiang,Tong, Hui,&Wang, Lixiang.(2015).Intramolecular charge-transfer emission from conjugated polymer nanoparticles: the terminal group effect on electronic and optical properties.POLYMER CHEMISTRY,6(12),2305-2311. |
| MLA | Wu, Xiaofu,et al."Intramolecular charge-transfer emission from conjugated polymer nanoparticles: the terminal group effect on electronic and optical properties".POLYMER CHEMISTRY 6.12(2015):2305-2311. |
入库方式： OAI收割
来源：化学研究所
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