Modular construction of macrocycle-based topological polymers via high-efficient thiol chemistry
文献类型：期刊论文
| 作者 | Zhao, Junfei1; Zhou, Yanyan1; Li, Yiwen2; Pan, Xiangqiang1; Zhang, Wei1; Zhou, Nianchen1; Zhang, Ke3; Zhang, Zhengbiao1; Zhu, Xiulin1 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:15页码:2879-2891 |
| 英文摘要 | Modular and precise construction of topological polymers with structural complexity is a prerequisite to understand the structure-property relationships of functional non-linear macromolecules. In this article, several examples of well-defined topological polymers are prepared by using two kinds of functionalized cyclic polymeric precursors via different high-efficient thiol-related chemistries. Firstly, multifunctional atom transfer radical polymerization (ATRP) initiators bearing alkyne and disulfide groups were elaborately prepared. Well-defined thiol-containing monocyclic and fused-bicyclic polymers via ATRP and Cu-catalyzed azide-alkyne cycloaddition (CuAAC) ring closure were then synthesized. Finally, by the utilization of thiol-containing monocyclic or fused-dicyclic polymers as building blocks, several kinds of macromolecules with tadpole-, spiro-shaped, fused-dicyclic tadpole and other topologies were successfully constructed via a modular mode. This study expands the scope of available macrocycle-based topological polymers and facilitates further diverse development of even more complex non-linear macromolecules via modular synthetic methodology. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28524]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou Key Lab Macromol Design & Precis Synth, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China 2.Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA 3.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Junfei,Zhou, Yanyan,Li, Yiwen,et al. Modular construction of macrocycle-based topological polymers via high-efficient thiol chemistry[J]. POLYMER CHEMISTRY,2015,6(15):2879-2891. |
| APA | Zhao, Junfei.,Zhou, Yanyan.,Li, Yiwen.,Pan, Xiangqiang.,Zhang, Wei.,...&Zhu, Xiulin.(2015).Modular construction of macrocycle-based topological polymers via high-efficient thiol chemistry.POLYMER CHEMISTRY,6(15),2879-2891. |
| MLA | Zhao, Junfei,et al."Modular construction of macrocycle-based topological polymers via high-efficient thiol chemistry".POLYMER CHEMISTRY 6.15(2015):2879-2891. |
入库方式： OAI收割
来源：化学研究所
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