Cyclic olefin copolymers of propylene with asymmetric Si-containing alpha,omega-diolefins: The tailored thermal and mechanical properties
文献类型：期刊论文
| 作者 | Wang, Bin1,2; Long, Ying-Yun1; Li, Yan-Guo1; Men, Yong-Feng1; Li, Yue-Sheng3 |
| 刊名 | POLYMER
 |
| 出版日期 | 2015-03-20 |
| 卷号 | 61页码:108-114 |
| 关键词 | Ziegler-Natta polymerization Polypropylene Thermoplastic elastomers |
| 英文摘要 | Activated by [Ph3C][B(C6F5)(4)], dimethylpyridylamidohafnium complex exhibited high performance in the copolymerization of propylene with 3,3-dimethyl-3-sila-1,5-hexadiene (DMSHD), producing high molecular weight random copolymers without pendent vinyl groups and cross-linking. The effects of the comonomer incorporation on chain microstructure, crystallinity, thermal properties and final mechanical properties were thoroughly explored by C-13 NMR, wide-angle X-ray scattering, DSC and tensile tests, respectively. The comparison of microstructure and mechanical properties between poly(propylene-co-DMSHD) and poly(propylene-co-HD) clearly indicates that the structures of the comonomers have significant effects on the chain microstructure, crystal structure and the final properties of the copolymers. All copolymer samples showed great enhancement of ductility and flexibility. It was noteworthy that the poorly crystalline copolymers containing small amount of crystalline in the amorphous matrix exhibit a typical thermoplastic behavior. Thus, a series of PP materials with different physical properties ranging from stiff plastics to semicrystalline flexible plastics to thermoplastic elastomers could be obtained by simply changing the monomer incorporation. (C) 2015 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28531]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Changchun Branch, Changchun 130022, Peoples R China 3.Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Bin,Long, Ying-Yun,Li, Yan-Guo,et al. Cyclic olefin copolymers of propylene with asymmetric Si-containing alpha,omega-diolefins: The tailored thermal and mechanical properties[J]. POLYMER,2015,61:108-114. |
| APA | Wang, Bin,Long, Ying-Yun,Li, Yan-Guo,Men, Yong-Feng,&Li, Yue-Sheng.(2015).Cyclic olefin copolymers of propylene with asymmetric Si-containing alpha,omega-diolefins: The tailored thermal and mechanical properties.POLYMER,61,108-114. |
| MLA | Wang, Bin,et al."Cyclic olefin copolymers of propylene with asymmetric Si-containing alpha,omega-diolefins: The tailored thermal and mechanical properties".POLYMER 61(2015):108-114. |
入库方式： OAI收割
来源：化学研究所
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