"Brill Transition" Shown by Green Material Poly(octamethylene carbonate)
文献类型：期刊论文
| 作者 | Zhao, Ti-Peng1,2; Ren, Xiang-Kui3; Zhu, Wen-Xiang1; Liang, Yong-Ri4; Li, Chun-Cheng1; Men, Yong-Feng5; Liu, Chen-Yang1; Chen, Er-Qiang6 |
| 刊名 | ACS MACRO LETTERS
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 4期号:3页码:317-321 |
| 英文摘要 | Poly(octamethylene carbonate) (POMC), as the eighth member of the newly developed biodegradable aliphatic polycarbonate family, demonstrates a reversible crystal crystal transition, which is highly similar to Brill transition extensively studied in the nylon family. With the dipole dipole interaction in POMC much weaker than the hydrogen bonding, POMC exhibits its "Brill transition" temperature at around 42 degrees C, much lower than nylons. The two crystalline structures of POMC at below and above the transition temperature can be identified. The transition of POMC is largely associated with the reversible conformation change of methylene sequences from trans-dominated at low temperatures to trans/gauche coexistence at high temperatures. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28463]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Joint Lab Polymer Sci & Mat, CAS Key Lab Engn Plast,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China 4.Beijing Inst Petrochem Technol, Coll Mat Sci & Engn, Beijing 102617, Peoples R China 5.Univ Chinese Acad Sci, Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 6.Peking Univ, Ctr Soft Matter Sci & Engn, Beijing Natl Lab Mol Sci,Coll Chem & Mol Engn, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Ti-Peng,Ren, Xiang-Kui,Zhu, Wen-Xiang,et al. "Brill Transition" Shown by Green Material Poly(octamethylene carbonate)[J]. ACS MACRO LETTERS,2015,4(3):317-321. |
| APA | Zhao, Ti-Peng.,Ren, Xiang-Kui.,Zhu, Wen-Xiang.,Liang, Yong-Ri.,Li, Chun-Cheng.,...&Chen, Er-Qiang.(2015)."Brill Transition" Shown by Green Material Poly(octamethylene carbonate).ACS MACRO LETTERS,4(3),317-321. |
| MLA | Zhao, Ti-Peng,et al.""Brill Transition" Shown by Green Material Poly(octamethylene carbonate)".ACS MACRO LETTERS 4.3(2015):317-321. |
入库方式： OAI收割
来源：化学研究所
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