Constrained formation of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridines and their cobalt(II) chloride complexes: synthesis, characterization and ethylene polymerization
文献类型：期刊论文
| 作者 | Ba, Junjun1,2,3; Du, Shizhen2,3; Yue, Erlin2,3; Hu, Xinquan1; Flisak, Zygmunt2,3,4; Sun, Wen-Hua2,3
|
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:41页码:32720-32729 |
| 英文摘要 | A series of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridine derivatives (L1-L5) was synthesized, and individually reacted with cobalt(II) chloride to form the corresponding cobalt chloride complexes (C1-C4). These compounds were characterized, and the single crystal X-ray diffraction for two representative cobalt complexes was carried out. The molecular structures indicate that 2,7-bis(arylimino)cyclopentapyridines act as tridentate ligands; however, one of the Co-N coordinative bonds is weak due to the spatial separation of nitrogen atoms. Upon activation with either MAO or MMAO, all cobalt complexes exhibit catalytic activities toward ethylene. Polymerization takes place in the presence of MAO with activities of approximately 10(4) g of PE per (mol of Co) per h, but oligomerization occurs in the presence of MMAO with the activities higher by one order of magnitude. The resultant products, either polyethylenes or oligomers, display high linearity. Relatively low activities observed for cobalt complexes discussed reflect the importance of the appropriate spatial arrangement of the three donor nitrogen atoms. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28601]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Opole Univ, Fac Chem, PL-45052 Opole, Poland |
| 推荐引用方式 GB/T 7714 | Ba, Junjun,Du, Shizhen,Yue, Erlin,et al. Constrained formation of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridines and their cobalt(II) chloride complexes: synthesis, characterization and ethylene polymerization[J]. RSC ADVANCES,2015,5(41):32720-32729. |
| APA | Ba, Junjun,Du, Shizhen,Yue, Erlin,Hu, Xinquan,Flisak, Zygmunt,&Sun, Wen-Hua.(2015).Constrained formation of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridines and their cobalt(II) chloride complexes: synthesis, characterization and ethylene polymerization.RSC ADVANCES,5(41),32720-32729. |
| MLA | Ba, Junjun,et al."Constrained formation of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridines and their cobalt(II) chloride complexes: synthesis, characterization and ethylene polymerization".RSC ADVANCES 5.41(2015):32720-32729. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。