1-(2,6-Dibenzhydryl-4-fluorophenylimino)-2-aryliminoacenaphthylylnickel Halides Highly Polymerizing Ethylene for the Polyethylenes with High Branches and Molecular Weights
文献类型：期刊论文
| 作者 | Fan, Linlin1,2,3; Du, Shizhen2,3; Guo, Cun-Yue1; Hao, Xiang2,3; Sun, Wen-Hua2,3
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| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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| 出版日期 | 2015-06-01 |
| 卷号 | 53期号:11页码:1369-1378 |
| 关键词 | 1 2-diiminoacenaphthylene branched cationic polymerization nickel complex polyethylene |
| 英文摘要 | A series of 1-(2,6-dibenzhydryl-4-fluorophenylimino)- 2-aryliminoacenaphthylene derivatives (L1-L5) and their halonickel complexes LNiX2 (X=Br, Ni1-Ni5; X=Cl, Ni6-Ni10) are synthesized and well characterized. The molecular structures of representative complexes Ni2 and Ni4 are confirmed as the distorted tetrahedron geometry around nickel atom by the single crystal X-ray diffraction. Upon activation with methylaluminoxane, all nickel complexes show high activities up to 1.49 x 10(7) g of PE (mol of Ni)(-1) h(-1) toward ethylene polymerization, producing polyethylenes with high branches and molecular weights up to 1.62 x 10(6) g mol(-1) as well as narrow polydispersity. (c) 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 1369-1378 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28602]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Linlin,Du, Shizhen,Guo, Cun-Yue,et al. 1-(2,6-Dibenzhydryl-4-fluorophenylimino)-2-aryliminoacenaphthylylnickel Halides Highly Polymerizing Ethylene for the Polyethylenes with High Branches and Molecular Weights[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2015,53(11):1369-1378. |
| APA | Fan, Linlin,Du, Shizhen,Guo, Cun-Yue,Hao, Xiang,&Sun, Wen-Hua.(2015).1-(2,6-Dibenzhydryl-4-fluorophenylimino)-2-aryliminoacenaphthylylnickel Halides Highly Polymerizing Ethylene for the Polyethylenes with High Branches and Molecular Weights.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,53(11),1369-1378. |
| MLA | Fan, Linlin,et al."1-(2,6-Dibenzhydryl-4-fluorophenylimino)-2-aryliminoacenaphthylylnickel Halides Highly Polymerizing Ethylene for the Polyethylenes with High Branches and Molecular Weights".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 53.11(2015):1369-1378. |
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来源：化学研究所
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