One-Step Synthesis of Au-Pd Alloy Nanodendrites and Their Catalytic Activity
文献类型：期刊论文
| 作者 | Shi, Lihua1,2; Wang, Aiqin1; Zhang, Tao1; Zhang, Bingsen3; Su, Dangsheng3; Li, Huanqiao4; Song, Yujiang4 |
| 刊名 | journal of physical chemistry c
 |
| 出版日期 | 2013-06-20 |
| 卷号 | 117期号:24页码:12526-12536 |
| 英文摘要 | au-pd bimetallic nanocrystals with well-defined dendritic morphology, uniform size, and homogeneous alloy structure were synthesized in an aqueous solution by using ascorbic acid as the reductant and triblock copolymer p123 as the stabilizing agent. in this synthesis, ascorbic acid played a key role in directing the nanodendritic morphology while the presence of pd was mandatory for the formation of well-defined nanodendrites. without pd, only faceted nanoparticles of gold were formed under the same reaction conditions. other reaction variables such as the addition sequence and the dropping rate of the metal precursors, the type and concentration of the stabilizing agents, and the reaction time and temperature were all found to affect the size uniformity and morphology perfectness to some extent. the au/pd atomic ratio could be tuned in a wide range without deteriorating the nanodendritic morphology. the as-prepared au-pd nanodendrites exhibited excellent catalytic activities toward electroxidation of methanol and reduction of 2-nitrophenol, and the catalytic performances could be effectively tuned by the au/pd ratio. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | pt bimetallic nanodendrites ; shape-controlled synthesis ; core-shell nanoparticles ; palladium nanocrystals ; hydrogen-peroxide ; electrocatalytic activity ; platinum nanostructures ; selective oxidation ; oxygen reduction ; highly efficient |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000320911100016 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137486]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Catalysis & Mat Div, Shenyang 110016, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Lihua,Wang, Aiqin,Zhang, Tao,et al. One-Step Synthesis of Au-Pd Alloy Nanodendrites and Their Catalytic Activity[J]. journal of physical chemistry c,2013,117(24):12526-12536. |
| APA | Shi, Lihua.,Wang, Aiqin.,Zhang, Tao.,Zhang, Bingsen.,Su, Dangsheng.,...&Song, Yujiang.(2013).One-Step Synthesis of Au-Pd Alloy Nanodendrites and Their Catalytic Activity.journal of physical chemistry c,117(24),12526-12536. |
| MLA | Shi, Lihua,et al."One-Step Synthesis of Au-Pd Alloy Nanodendrites and Their Catalytic Activity".journal of physical chemistry c 117.24(2013):12526-12536. |
入库方式： OAI收割
来源：大连化学物理研究所
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