Formation of 3-pentanone via ethylene hydroformylation over Co/activated carbon catalyst
文献类型：期刊论文
| 作者 | Song, Xiangen1,3; Ding, Yunjie1,2; Chen, Weimiao1; Dong, Wenda1,3; Pei, Yanpeng1,3; Zang, Juan1,3; Yan, Li1; Lu, Yuan1 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2013-02-15 |
| 卷号 | 452页码:155-162 |
| 关键词 | Ethylene hydroformylation Cobalt carbonyl Activated carbon 3-Pentanone |
| 英文摘要 | in ethylene hydroformylation over co/activated carbon (ac) catalyst, in addition to propanal, 3-pentanone was formed for the first time as one of a main product over heterogeneous cobalt catalyst. it was interesting to find that the properties of the supports, including both micropore proportion and the carbonaceous materials, are key factors in the formation of ketones. based on the characterization results, cobalt carbonyl species was confirmed to be related with the formation of ketones on the surface of heterogeneous co based catalysts. the small particle of cobalt and the high ratio of chemisorbed co/h-2 might favor the formation of cobalt carbonyl clusters on the activated carbon supported cobalt catalysts. (c) 2012 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | rh active-carbon ; cobalt catalysts ; ethene hydroformylation ; rh/active-carbon ; pentan-3-one formation ; sulfide catalysts ; oxygenate fuels ; metal particles ; monoxide ; ketones |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000315013200020 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137505]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Xiangen,Ding, Yunjie,Chen, Weimiao,et al. Formation of 3-pentanone via ethylene hydroformylation over Co/activated carbon catalyst[J]. applied catalysis a-general,2013,452:155-162. |
| APA | Song, Xiangen.,Ding, Yunjie.,Chen, Weimiao.,Dong, Wenda.,Pei, Yanpeng.,...&Lu, Yuan.(2013).Formation of 3-pentanone via ethylene hydroformylation over Co/activated carbon catalyst.applied catalysis a-general,452,155-162. |
| MLA | Song, Xiangen,et al."Formation of 3-pentanone via ethylene hydroformylation over Co/activated carbon catalyst".applied catalysis a-general 452(2013):155-162. |
入库方式： OAI收割
来源：大连化学物理研究所
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