Identification of Fe-2(mu-O) and Fe-2(mu-O)(2) sites in Fe/ZSM-35 by in situ resonance Raman spectroscopy
文献类型：期刊论文
| 作者 | Wang, Junying1,2; Li, Guanna1; Ju, Xiaohua1; Xia, Haian1; Fan, Fengtao1; Wang, Junhu1; Feng, Zhaochi1; Li, Can1 |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2013-05-01 |
| 卷号 | 301页码:77-82 |
| 关键词 | Resonance Raman spectroscopy Fe/ZSM-35 Active iron site |
| 英文摘要 | the structure of the active iron site in fe/zsm-35 was investigated by in situ resonance raman spectroscopy combined with mossbauer spectroscopy and dft calculations. in situ uv resonance raman spectra coupled with fe-57 mossbauer spectra suggest that the active fe site for n2o decomposition is an fe-2(mu-o) site, characterized by a raman band at 875 cm(-1). in situ visible resonance raman spectra reveals the formation of an fe-2(mu-o)(2) site with a feature raman band at 730 cm(-1) upon n2o reacts with the fe-2(mu-o) site. the raman band intensity at 730 cm(-1) is decreasing after exposing the fe-2(mu-o)(2) site to ch4 due to the formation of methoxide species which mimics the biocatalysis of soluble methane monooxygenase (smmo). crown copyright (c) 2013 published by elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | low fe content ; active-sites ; mossbauer-spectroscopy ; n2o decomposition ; deposited oxygen ; iron ; zeolite ; framework ; ferrierite ; fe-zsm-5 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000318332300009 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137515]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Junying,Li, Guanna,Ju, Xiaohua,et al. Identification of Fe-2(mu-O) and Fe-2(mu-O)(2) sites in Fe/ZSM-35 by in situ resonance Raman spectroscopy[J]. journal of catalysis,2013,301:77-82. |
| APA | Wang, Junying.,Li, Guanna.,Ju, Xiaohua.,Xia, Haian.,Fan, Fengtao.,...&Li, Can.(2013).Identification of Fe-2(mu-O) and Fe-2(mu-O)(2) sites in Fe/ZSM-35 by in situ resonance Raman spectroscopy.journal of catalysis,301,77-82. |
| MLA | Wang, Junying,et al."Identification of Fe-2(mu-O) and Fe-2(mu-O)(2) sites in Fe/ZSM-35 by in situ resonance Raman spectroscopy".journal of catalysis 301(2013):77-82. |
入库方式： OAI收割
来源：大连化学物理研究所
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