Molar heat capacity and thermodynamic properties of Lu(C5H9NO4)(C3H4N2)(6)(ClO4)(3)center dot 5HClO(4)center dot 10H(2)O
文献类型：期刊论文
| 作者 | Lv, X. -C.1; Tan, Z. -C.2,3,4; Gao, X. -H.1; Chen, P.1 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2013 |
| 卷号 | 111期号:1页码:971-976 |
| 关键词 | Lu(C5H9NO4)(C3H4N2)(6)(ClO4)(3)center dot 5HClO(4)center dot 10H(2)O Adiabatic calorimetry Low-temperature heat capacity Phase transition Thermal analysis |
| 英文摘要 | a complex of lutetium perchloric acid coordinated with l-glutaminic acid (c5h9no4) and imidazole (c3h4n2), lu(c5h9no4)(c3h4n2)(6)(clo4)(3)center dot 5hclo(4)center dot 10h(2)o was synthesized and characterized. thermodynamic properties of the complex were studied with an adiabatic calorimeter (ac) from 80 to 390 k and differential scanning calorimetry (dsc) from 100 to 300 k. two thermal abnormalities were discovered at 220.34 and 248.47 k, which were deduced to be phase transitions. one was interpreted as a freezing-in phenomenon of the reorientational motion of clo4 (-) ions and the other was attributed to the orientational order/disorder process of clo4 (-) ions. the low-temperature molar heat capacities were measured by ac and the thermodynamic functions [h (t) - h (298.15)] and [s (t) - s (298.15)] were derived in the temperature range from 80 to 390 k with temperature interval of 5 k. thermal decomposition behavior of the complex was studied by thermogravimetric analysis and dsc. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | thermal-stability ; crystalline ; complex |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000313207400125 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137518]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, X. -C.,Tan, Z. -C.,Gao, X. -H.,et al. Molar heat capacity and thermodynamic properties of Lu(C5H9NO4)(C3H4N2)(6)(ClO4)(3)center dot 5HClO(4)center dot 10H(2)O[J]. journal of thermal analysis and calorimetry,2013,111(1):971-976. |
| APA | Lv, X. -C.,Tan, Z. -C.,Gao, X. -H.,&Chen, P..(2013).Molar heat capacity and thermodynamic properties of Lu(C5H9NO4)(C3H4N2)(6)(ClO4)(3)center dot 5HClO(4)center dot 10H(2)O.journal of thermal analysis and calorimetry,111(1),971-976. |
| MLA | Lv, X. -C.,et al."Molar heat capacity and thermodynamic properties of Lu(C5H9NO4)(C3H4N2)(6)(ClO4)(3)center dot 5HClO(4)center dot 10H(2)O".journal of thermal analysis and calorimetry 111.1(2013):971-976. |
入库方式： OAI收割
来源：大连化学物理研究所
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