Rh(III)-catalyzed oxidative synthesis of pyrazoles from azomethines and acrylamides
文献类型:期刊论文
作者 | Zhen Wencui1,2; Du Zhengyin1; Li Xingwei2 |
刊名 | chinese journal of catalysis
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出版日期 | 2013-04-01 |
卷号 | 34期号:4页码:679-683 |
关键词 | Rhodium(III) C-H bond activation Acrylamide Azomethine C-N coupling Pyrazole |
英文摘要 | a cationic rh(iii) complex has been developed to catalyze the oxidative coupling of azomethine imines to acrylamides, to give trisubstituted pyrazoles in moderate yield. in this process, the olefinic c-h bond of the acrylamide undergoes c-h activation, and the reaction subsequently proceeds via a different selectivity to that reported for the coupling of acrylate esters. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | h bond-cleavage ; n-heterocyclic carbenes ; c-h ; internal alkynes ; catalyzed hydroformylation ; rhodium catalysis ; benzoic-acids ; activation ; coupling/cyclization ; benzamides |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000318750500007 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137521] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecoenvironm Related Polymer Mat, Minist Educ,Gansu Key Lab Polymer Mat, Lanzhou 730070, Gansu, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Zhen Wencui,Du Zhengyin,Li Xingwei. Rh(III)-catalyzed oxidative synthesis of pyrazoles from azomethines and acrylamides[J]. chinese journal of catalysis,2013,34(4):679-683. |
APA | Zhen Wencui,Du Zhengyin,&Li Xingwei.(2013).Rh(III)-catalyzed oxidative synthesis of pyrazoles from azomethines and acrylamides.chinese journal of catalysis,34(4),679-683. |
MLA | Zhen Wencui,et al."Rh(III)-catalyzed oxidative synthesis of pyrazoles from azomethines and acrylamides".chinese journal of catalysis 34.4(2013):679-683. |
入库方式: OAI收割
来源:大连化学物理研究所
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