Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction
文献类型：期刊论文
| 作者 | Cao, Hujun1,2,3; Chua, Yongshen2; Zhang, Yao4; Xiong, Zhitao2; Wu, Guotao2; Qiu, Jieshan1; Chen, Ping2 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2013-08-21 |
| 卷号 | 38期号:25页码:10446-10452 |
| 关键词 | Hydrogen storage Magnesium amide Ammonia borane Ball milling |
| 英文摘要 | ball milling the mixture of mg(nh2)(2), lih and nh3bh3 in a molar ratio of 1:3:1 results in the direct liberation of 9.6 wt% h-2 (11 equiv. h), which is superior to binary systems such as lih ab (6 equiv. h), ab-mg(nh2)(2) (no h-2 release) and lih-mg(nh2)(2) (4 equiv. h), respectively. the overall dehydrogenation is a three-step process in which lih firstly reacts with ab to yield linh2bh3 and linh2bh3 further reacts with mg(nh2)(2) to form limgbn3h3. limgbn3h3 subsequently interacts with additional 2 equivalents of lih to form li3bn2 and mgnh as well as hydrogen. copyright (c) 2013, the authors. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | n-h system ; hydrogen storage properties ; ammonia-borane ; lithium ; desorption ; absorption ; sorption ; libh4 ; lih |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000324563100031 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137543]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Liaoning Key Lab Energy Mat & Chem Engn, State Key Lab Fine Chem, Carbon Res Lab, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Southeast Univ, Sch Mat Sci & Engn, Nanjing 211189, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Hujun,Chua, Yongshen,Zhang, Yao,et al. Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction[J]. international journal of hydrogen energy,2013,38(25):10446-10452. |
| APA | Cao, Hujun.,Chua, Yongshen.,Zhang, Yao.,Xiong, Zhitao.,Wu, Guotao.,...&Chen, Ping.(2013).Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction.international journal of hydrogen energy,38(25),10446-10452. |
| MLA | Cao, Hujun,et al."Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction".international journal of hydrogen energy 38.25(2013):10446-10452. |
入库方式： OAI收割
来源：大连化学物理研究所
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