Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol
文献类型：期刊论文
| 作者 | Jia, Xiuquan1,2; Ma, Jiping1; Che, Penghua1,2; Lu, Fang1; Miao, Hong1; Gao, Jin1; Xu, Jie1 |
| 刊名 | journal of energy chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 22期号:1页码:93-97 |
| 关键词 | carbohydrates 5-ethoxymethylfurfural catalysis Lewis acid |
| 英文摘要 | direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural (emf) catalyzed by lewis acid in ethanol was investigated. it was found that bf3 center dot(et)(2)o was favorable for 5-hydroxymethylfurfural (hmf) etherification to emf. bf3 center dot(et)(2)o combination with alcl3 center dot 6h(2)o with the molar ratio of 1 was an effective catalyst system for synthesis of emf from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of emf yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical |
| 研究领域[WOS] | chemistry ; energy & fuels ; engineering |
| 关键词[WOS] | lignocellulosic biomass ; cellulose ; derivatives ; chemicals ; 2,5-diformylfuran ; etherification ; alcohol ; biofuel ; glucose ; system |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000318050700013 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137585]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Xiuquan,Ma, Jiping,Che, Penghua,et al. Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol[J]. journal of energy chemistry,2013,22(1):93-97. |
| APA | Jia, Xiuquan.,Ma, Jiping.,Che, Penghua.,Lu, Fang.,Miao, Hong.,...&Xu, Jie.(2013).Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol.journal of energy chemistry,22(1),93-97. |
| MLA | Jia, Xiuquan,et al."Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol".journal of energy chemistry 22.1(2013):93-97. |
入库方式： OAI收割
来源：大连化学物理研究所
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