Low-temperature heat capacities, and thermodynamic properties of solid-solid phase change material bis(1-octylammonium) tetrachlorocuprate
文献类型：期刊论文
| 作者 | Lu, D. F.1; Di, You-Ying1; Tan, Z. C.2; Dou, J. M.1 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2013 |
| 卷号 | 111期号:1页码:213-218 |
| 关键词 | Phase change material Adiabatic calorimetry Low-temperature heat capacities Solid-solid phase transition Thermodynamic function |
| 英文摘要 | a new crystalline complex (c8h17nh3)(2)cucl4(s) (abbreviated as c8cu(s)) was synthesized by liquid phase reaction. chemical analysis, elemental analysis, and x-ray crystallography were applied to characterize the composition and crystal structure of the complex. low-temperature heat capacities of the complex were measured by a precision automatic adiabatic calorimeter over the temperatures ranging from 78 to 395 k, and two solid-solid phase changes appeared in the heat capacity curve. the temperatures, molar enthalpies and entropies of the two phase transitions of the complex were determined to be: t (trs, 1) = 309.4 +/- a 0.35 k, delta(trs) h (m, 1) = 16.55 +/- a 0.41 kj mol(-1), and delta(trs) s (m, 1) = 53.49 +/- a 1.3 j k-1 mol(-1) for the first peak; t (trs, 2) = 338.5 +/- a 0.63 k, delta(trs) h (m, 2) = 6.500 +/- a 0.10 kj mol(-1), and delta(trs) s (m, 2) = 19.20 +/- a 0.28 j k-1 mol(-1) for the second peak. two polynomial equations of the heat capacities as a function of the temperature were fitted by least-square method. smoothed heat capacities and thermodynamic functions of the complex relative to the standard reference temperature of 298.15 k were calculated based on the fitted polynomial equations. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | tetrachlorozincate ; transitions ; storage |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000313207400027 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137600]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Shandong Prov Key Lab Chem Energy Storage & Novel, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Energy Storage & Thermochem Lab, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, D. F.,Di, You-Ying,Tan, Z. C.,et al. Low-temperature heat capacities, and thermodynamic properties of solid-solid phase change material bis(1-octylammonium) tetrachlorocuprate[J]. journal of thermal analysis and calorimetry,2013,111(1):213-218. |
| APA | Lu, D. F.,Di, You-Ying,Tan, Z. C.,&Dou, J. M..(2013).Low-temperature heat capacities, and thermodynamic properties of solid-solid phase change material bis(1-octylammonium) tetrachlorocuprate.journal of thermal analysis and calorimetry,111(1),213-218. |
| MLA | Lu, D. F.,et al."Low-temperature heat capacities, and thermodynamic properties of solid-solid phase change material bis(1-octylammonium) tetrachlorocuprate".journal of thermal analysis and calorimetry 111.1(2013):213-218. |
入库方式： OAI收割
来源：大连化学物理研究所
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