A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of alpha,beta-unsaturated ketones to allylic alcohol
文献类型：期刊论文
| 作者 | Lu, Sheng-Mei1,2; Gao, Qiang1; Li, Jun1; Liu, Yan1; Li, Can1 |
| 刊名 | tetrahedron letters
 |
| 出版日期 | 2013-12-18 |
| 卷号 | 54期号:51页码:7013-7016 |
| 关键词 | Ruthenium Biphosphinobioxazoline Hydrogenation Unsaturated ketones Allylic alcohol |
| 英文摘要 | a robust and stable ru-biphosphinobioxazoline catalyst system is discovered for the highly enantioselective hydrogenation of enones to allylic alcohols. a series of acyclic alpha,beta-unsaturated ketones react well affording the desired products in high yields (up to 98%) and enantioselectivities (up to 98% ee). simple manipulation process and tolerance of water and air make this catalysis more practical and appealing. (c) 2013 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | highly enantioselective hydrogenation ; stereoselective hydrogenation ; heteroaromatic-compounds ; ruthenium(ii) complex ; aromatic ketones ; chiral ligand ; hydrosilylation ; efficient ; alpha |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000327577200008 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137645]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Sheng-Mei,Gao, Qiang,Li, Jun,et al. A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of alpha,beta-unsaturated ketones to allylic alcohol[J]. tetrahedron letters,2013,54(51):7013-7016. |
| APA | Lu, Sheng-Mei,Gao, Qiang,Li, Jun,Liu, Yan,&Li, Can.(2013).A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of alpha,beta-unsaturated ketones to allylic alcohol.tetrahedron letters,54(51),7013-7016. |
| MLA | Lu, Sheng-Mei,et al."A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of alpha,beta-unsaturated ketones to allylic alcohol".tetrahedron letters 54.51(2013):7013-7016. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。