The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell
文献类型:期刊论文
作者 | Zhang, Linsong1,2; Shao, Zhi-Gang1; Wang, Xunying1,2; Yu, Hongmei1; Liu, Sa1,2; Yi, Baolian1 |
刊名 | journal of power sources
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出版日期 | 2013-11-15 |
卷号 | 242页码:15-22 |
关键词 | Hydrogen bromine fuel cell Graphite felt electrode Surface modification Electrochemistry |
英文摘要 | graphite felt is used as the bromine electrode in h-2/br-2 fuel cell, which is surface modified by acidic oxidation and thermal oxidation for improving cell performance. the structure, composition, electrochemical properties and performances of the modified electrodes are characterized with x-ray diffraction, scanning electron microscopy, x-ray photoelectron spectroscopy, electrochemistry impedance spectroscopy and single cell polarization curves. the maximum power densities are improved from the original 0.51 to 0.62 and 0.69 w cm(-2) after acidic oxidized at 80 degrees c for 8 h and thermal oxidized at 500 degrees c for 5 h, respectively. the performance improvement may be attributed to the increase in oxygen-containing functional groups and surface area which could increase the electrochemical catalytic activity and thus decrease the charge transfer resistance. however, the ohmic resistance and charge transfer resistance increase after superabundant oxidation, which causes badly deteriorates in cell performance. (c) 2013 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | electrochemistry ; energy & fuels |
研究领域[WOS] | electrochemistry ; energy & fuels |
关键词[WOS] | redox flow battery ; walled carbon nanotubes ; hydrogen electrode ; energy-storage ; performance ; h2so4 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000323628100003 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137647] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Linsong,Shao, Zhi-Gang,Wang, Xunying,et al. The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell[J]. journal of power sources,2013,242:15-22. |
APA | Zhang, Linsong,Shao, Zhi-Gang,Wang, Xunying,Yu, Hongmei,Liu, Sa,&Yi, Baolian.(2013).The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell.journal of power sources,242,15-22. |
MLA | Zhang, Linsong,et al."The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell".journal of power sources 242(2013):15-22. |
入库方式: OAI收割
来源:大连化学物理研究所
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