中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell

文献类型:期刊论文

作者Zhang, Linsong1,2; Shao, Zhi-Gang1; Wang, Xunying1,2; Yu, Hongmei1; Liu, Sa1,2; Yi, Baolian1
刊名journal of power sources
出版日期2013-11-15
卷号242页码:15-22
关键词Hydrogen bromine fuel cell Graphite felt electrode Surface modification Electrochemistry
英文摘要graphite felt is used as the bromine electrode in h-2/br-2 fuel cell, which is surface modified by acidic oxidation and thermal oxidation for improving cell performance. the structure, composition, electrochemical properties and performances of the modified electrodes are characterized with x-ray diffraction, scanning electron microscopy, x-ray photoelectron spectroscopy, electrochemistry impedance spectroscopy and single cell polarization curves. the maximum power densities are improved from the original 0.51 to 0.62 and 0.69 w cm(-2) after acidic oxidized at 80 degrees c for 8 h and thermal oxidized at 500 degrees c for 5 h, respectively. the performance improvement may be attributed to the increase in oxygen-containing functional groups and surface area which could increase the electrochemical catalytic activity and thus decrease the charge transfer resistance. however, the ohmic resistance and charge transfer resistance increase after superabundant oxidation, which causes badly deteriorates in cell performance. (c) 2013 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]electrochemistry ; energy & fuels
研究领域[WOS]electrochemistry ; energy & fuels
关键词[WOS]redox flow battery ; walled carbon nanotubes ; hydrogen electrode ; energy-storage ; performance ; h2so4
收录类别SCI
语种英语
WOS记录号WOS:000323628100003
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/137647]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Linsong,Shao, Zhi-Gang,Wang, Xunying,et al. The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell[J]. journal of power sources,2013,242:15-22.
APA Zhang, Linsong,Shao, Zhi-Gang,Wang, Xunying,Yu, Hongmei,Liu, Sa,&Yi, Baolian.(2013).The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell.journal of power sources,242,15-22.
MLA Zhang, Linsong,et al."The characterization of graphite felt electrode with surface modification for H-2/Br-2 fuel cell".journal of power sources 242(2013):15-22.

入库方式: OAI收割

来源:大连化学物理研究所

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