1-Butene metathesis over Mo/mordenite-alumina catalyst: Effect of sodium exchange degree in mordenite zeolite
文献类型：期刊论文
| 作者 | Li, Xiujie; Zhang, Dazhou; Zhu, Xiangxue; Chen, Fucun; Liu, Shenglin; Xie, Sujuan; Xu, Longya |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 372页码:121-127 |
| 关键词 | 1-Butene Propene Olefin metathesis Molybdenum Mordenite-alumina |
| 英文摘要 | a series of mo/mordenite-alumina catalysts with progressive sodium exchange degrees in mordenite were prepared and their performance in 1-butene metathesis reaction was evaluated. significant variations in product distribution and catalytic activity were observed when the exchange degree of mordenite changed. as revealed by nh3-tpd and h-1 mas nmr results, the acid site density and distribution over the catalysts were directly related to the degree of ion-exchange of sodium in mordenite. the change of support acidity led to different anchoring modes and dispersion of mo species on the support which further resulted in the different reduction behavior of mo species under olefin atmosphere. a good correlation between product distribution and properties of the catalysts was proposed. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | solid-state nmr ; olefin metathesis ; heterogeneous catalysts ; supported molybdenum ; tungsten-oxide ; silica-alumina ; h-mordenite ; propene ; performance ; oxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000318138300018 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137648]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiujie,Zhang, Dazhou,Zhu, Xiangxue,et al. 1-Butene metathesis over Mo/mordenite-alumina catalyst: Effect of sodium exchange degree in mordenite zeolite[J]. journal of molecular catalysis a-chemical,2013,372:121-127. |
| APA | Li, Xiujie.,Zhang, Dazhou.,Zhu, Xiangxue.,Chen, Fucun.,Liu, Shenglin.,...&Xu, Longya.(2013).1-Butene metathesis over Mo/mordenite-alumina catalyst: Effect of sodium exchange degree in mordenite zeolite.journal of molecular catalysis a-chemical,372,121-127. |
| MLA | Li, Xiujie,et al."1-Butene metathesis over Mo/mordenite-alumina catalyst: Effect of sodium exchange degree in mordenite zeolite".journal of molecular catalysis a-chemical 372(2013):121-127. |
入库方式： OAI收割
来源：大连化学物理研究所
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