Superior electrode performance of LiFePO4/C composite prepared by an in situ polymerization restriction method
文献类型：期刊论文
| 作者 | Chen, Jian1; Zou, Yong-Cun1; Zhang, Feng2; Zhang, Yuan-Chun1; Guo, Fei-Fan1; Li, Guo-Dong1 |
| 刊名 | journal of alloys and compounds
 |
| 出版日期 | 2013-06-25 |
| 卷号 | 563页码:264-268 |
| 关键词 | Electrode materials Microstructure Coating materials Precipitation |
| 英文摘要 | the lifepo4/c composite is prepared by heating the mixture of resorcinol-formaldehyde gel and fepo4, synthesized by an in situ polymerization restriction method, and lithium acetate dihydrate in the atmosphere of nitrogen. the physical and electrochemical properties of the lifepo4/c composite are investigated by x-ray diffraction, raman spectroscopy, thermogravimetric analysis, scanning electron microscopy, transmission electron microscopy and electrochemical measurements. the discharge capacity of lifepo4 is as high as 155.6 ma h g(-1) in the first cycle at 0.5c, and it could remain 144.0 ma h g(-1) after 50 cycles. even at the high rates of 10c, 20c and 50c, the initial discharge capacities of the electrodes exhibit 115.6 ma h g(-1), 84.5 ma h g(-1) and 67.8 ma h g(-1), and the electrodes deliver capacity retention of 89.5%, 90.9% and 85.7% after 1000 cycles, respectively. the outstanding electrochemical performance could be attributed to the small particle size and good electronic conductivity of the composite. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary ; metallurgy & metallurgical engineering |
| 研究领域[WOS] | chemistry ; materials science ; metallurgy & metallurgical engineering |
| 关键词[WOS] | lithium-ion batteries ; high-rate capability ; electrochemical performance ; cathode materials ; hydrothermal synthesis ; carbon ; nanocomposite ; nanoparticles ; microspheres ; enhancement |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317269300047 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137660]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Adv Rechargeable Batteries, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Jian,Zou, Yong-Cun,Zhang, Feng,et al. Superior electrode performance of LiFePO4/C composite prepared by an in situ polymerization restriction method[J]. journal of alloys and compounds,2013,563:264-268. |
| APA | Chen, Jian,Zou, Yong-Cun,Zhang, Feng,Zhang, Yuan-Chun,Guo, Fei-Fan,&Li, Guo-Dong.(2013).Superior electrode performance of LiFePO4/C composite prepared by an in situ polymerization restriction method.journal of alloys and compounds,563,264-268. |
| MLA | Chen, Jian,et al."Superior electrode performance of LiFePO4/C composite prepared by an in situ polymerization restriction method".journal of alloys and compounds 563(2013):264-268. |
入库方式： OAI收割
来源：大连化学物理研究所
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