An abnormal phenomenon on O-2(a(1)Delta) deactivation by deuterated alcohols
文献类型：期刊论文
| 作者 | Wang, Junhui; Leng, Jing; Yang, Heping; Sha, Guohe; Zhang, Cunhao |
| 刊名 | chemical physics letters
 |
| 出版日期 | 2013-09-17 |
| 卷号 | 583页码:14-17 |
| 英文摘要 | the deactivation rate constants (k(delta)) of o-2(a(1)delta) by several gaseous alcohols were measured using a quasi-static method. the results indicate that the gaseous k(delta) values for normal alcohols are smaller than their corresponding liquid-phase data, well consistent with schmidt's model. however, for deuterated alcohols, an abnormal phenomenon that their gaseous k(delta) values are evidently larger than their corresponding liquid-phase data was first observed. it is likely related to the o-d bonds in their molecules which can form more stable liquid-phase clusters via intermolecular hydrogen bonds and exhibit different vibrational constants in gas and liquid phase. (c) 2013 elsevier b. v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | singlet molecular-oxygen ; rate constants ; spectroscopy ; temperature ; chemistry ; solvent ; systems ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000324304600003 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137668]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Junhui,Leng, Jing,Yang, Heping,et al. An abnormal phenomenon on O-2(a(1)Delta) deactivation by deuterated alcohols[J]. chemical physics letters,2013,583:14-17. |
| APA | Wang, Junhui,Leng, Jing,Yang, Heping,Sha, Guohe,&Zhang, Cunhao.(2013).An abnormal phenomenon on O-2(a(1)Delta) deactivation by deuterated alcohols.chemical physics letters,583,14-17. |
| MLA | Wang, Junhui,et al."An abnormal phenomenon on O-2(a(1)Delta) deactivation by deuterated alcohols".chemical physics letters 583(2013):14-17. |
入库方式： OAI收割
来源：大连化学物理研究所
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